[N,N,N',N'-Tetra-kis(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine]-iron(II) bis-(perchlorate) methanol solvate.
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 5): m531, 2011 May 01.
Article
em En
| MEDLINE
| ID: mdl-21754271
ABSTRACT
In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octa-hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N',N'-tetra-kis-(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol mol-ecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539â
(14) and 0.461â
(14). N-Hâ¯O and C-Hâ¯O hydrogen bonds, as well as π-π stacking inter-actions between the imidazol rings and between the imidazol and benzene rings [centroid-centroid distances = 3.714â
(2) and 3.705â
(2)â
Å] give rise to a three-dimensional network.
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MEDLINE
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En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2011
Tipo de documento:
Article