4-(2-Chloro-anilino)-3-phenyl-furan-2(5H)-one.
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 11): o3091, 2011 Nov.
Article
em En
| MEDLINE
| ID: mdl-22220096
The title compound, C(16)H(12)ClNO(2), featuring a furan-2(5H)-one (γ-butyrolactone) core, contains two mol-ecules (A and B) in the asymmetric unit, with different dihedral angles between the central ring and the pendant phenyl and chloro-benzene rings [43.33â
(8) and 20.16â
(8)°, respectively, for A, and 47.79â
(8) and 13.87â
(8)°, respectively, for B]. In the crystal, the A mol-ecules are linked into [001] chains by single C-Hâ¯O inter-actions. The B mol-ecules also form [001] chains, but their relative orientations in the chains are quite different to those of the A mol-ecules so that adjacent B mol-ecules are linked by two C-Hâ¯O hydrogen bonds. Finally, C-Hâ¯O inter-actions and aromatic π-π stacking contacts [centroid-centroid separations = 3.754â
(1) and 3.817â
(1)â
Å] link the chains into a two-dimensional array parallel to (010).
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MEDLINE
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En
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Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2011
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Article