N-(2-Carb-oxy-eth-yl)-2,5-dide-oxy-2,5-imino-d-mannonic acid [(3R,4R,5R)-1-(2-carb-oxy-eth-yl)-3,4-dihy-droxy-5-hy-droxy-methyl-l-proline].
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 10): o2865-6, 2012 Oct 01.
Article
em En
| MEDLINE
| ID: mdl-23125666
ABSTRACT
The absolute stereochemistry of the title compound, C(9)H(15)NO(7), was determined from the use of d-glucuronolactone as the starting material. The compound crystallizes as the zwitterion. The five-membered ring adopts an envelope conformation with the -CH(2)OH-substituted C atom forming the flap. An intramolecular N-Hâ¯O hydrogen-bond occurs. In the crystal, the compound exists as a three-dimensional O-Hâ¯O intermolecular hydrogen-bonded network with each mol-ecule acting as a donor and acceptor for four hydrogen bonds.
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Bases de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
Reino Unido