Using N-tosylhydrazone as a double nucleophile in the palladium-catalyzed cross-coupling reaction to synthesize allylic sulfones.
Chemistry
; 20(49): 16093-6, 2014 Dec 01.
Article
em En
| MEDLINE
| ID: mdl-25339137
ABSTRACT
Without extra addition of sulfinate salt, allylic sulfones were synthesized by palladium-catalyzed cross-coupling of aryl iodide with N-tosylhydrazone. In this transformation, not only the diazo compound but also the sulfinate salt, which were both generated in situ from base-mediated decomposition of the N-tosylhydrazone, was used as nucleophilic partner.
Palavras-chave
Texto completo:
1
Bases de dados:
MEDLINE
Assunto principal:
Paládio
/
Sulfonas
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Compostos de Tosil
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Compostos Alílicos
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Hidrazonas
Idioma:
En
Revista:
Chemistry
Assunto da revista:
QUIMICA
Ano de publicação:
2014
Tipo de documento:
Article