Polyboramines for Hydrogen Release: Polymers Containing Lewis Pairs in their Backbone.
Angew Chem Int Ed Engl
; 54(52): 15744-9, 2015 Dec 21.
Article
em En
| MEDLINE
| ID: mdl-26563914
ABSTRACT
The one-step polycondensation of diamines and diboranes triggered by the inâ
situ deprotonation of the diammonium salts and concomitant reduction of bisboronic acids leads to the assembly of polymer chains through multiple Lewis pairing in their backbone. These new polyboramines are dihydrogen reservoirs that can be used for the hydrogenation of imines and carbonyl compounds. They also display a unique dihydrogen thermal release profile that is a direct consequence of the insertion of the amine-borane linkages in the polymeric backbone.
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MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2015
Tipo de documento:
Article