Using ß-cyclodextrin/attapulgite-immobilized ionic liquid as sorbent in dispersive solid-phase microextraction to detect the benzoylurea insecticide contents of honey and tea beverages.
Food Chem
; 197 Pt B: 1064-72, 2016 Apr 15.
Article
em En
| MEDLINE
| ID: mdl-26675842
ABSTRACT
A green, simple, inexpensive dispersive solid-phase microextraction method coupled with high-performance liquid chromatography was developed for rapid screening and selective recognition of benzoylurea insecticides (BUs) in honey and tea beverages. A novel adsorbent, ionic liquid (IL)-modified ß-cyclodextrin/attapulgite (ß-CD/ATP), was prepared by immobilizing IL on the surface of ß-CD/ATP. A series of demanding extraction conditions were investigated through the experimental design. Under optimum conditions, the limits of detection for the analytes varied from 0.12 to 0.21 µg L(-1). The enrichment factors ranged from 112 to 150 folds. Linearities in the range of 5-500 ng m L(-1) were achieved for four BUs, while the correlation coefficients ranged from 0.9997 to 1.0000 and the recoveries from 84.5% to 104.7%. The precision of this method for the four BUs corresponded to intra-day and inter-day RSDs% lower than 3.85%. Finally, the proposed technique was applied for the preconcentration of the BUs from real samples with satisfactory results.
Palavras-chave
Attapulgite; Attapulgite (PubChem CID: 56842194); Benzoylurea insecticides; Chlorfluazuron (PubChem CID: 91708); Dispersive solid-phase microextraction; Flufenoxuron (PubChem CID: 91766); Hexaflumuron (PubChem CID: 91741); High-performance liquid chromatography; Ionic liquid; Lufenuron (PubChem CID: 71777); PlackettBurman design; ß-Cyclodextrin (PubChem CID: 444041)
Texto completo:
1
Bases de dados:
MEDLINE
Assunto principal:
Compostos de Fenilureia
/
Chá
/
Líquidos Iônicos
/
Microextração em Fase Sólida
/
Mel
/
Inseticidas
Idioma:
En
Revista:
Food Chem
Ano de publicação:
2016
Tipo de documento:
Article
País de afiliação:
China