Construction of Optically Active Isotwistanes and Aminocyclitols Using Chiral Cyclohexadiene as a Common Intermediate.
Chem Pharm Bull (Tokyo)
; 64(10): 1474-1483, 2016 Oct 01.
Article
em En
| MEDLINE
| ID: mdl-27452927
ABSTRACT
We have developed a new method for synthesizing chiral isotwistane and homoisotwistane skeletons as well as aminocyclitols in a highly stereoselective manner. These results were achieved through the use of a common intermediate, which was derived from the ytterbium-catalyzed asymmetric Diels-Alder reaction of Danishefsky diene.
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Bases de dados:
MEDLINE
Assunto principal:
Hidrocarbonetos Aromáticos com Pontes
/
Alcanos
/
Cicloexenos
/
Ciclitóis
Idioma:
En
Revista:
Chem Pharm Bull (Tokyo)
Ano de publicação:
2016
Tipo de documento:
Article