Metal-organic framework-derived mesoporous octahedral copper oxide/titania composites for high-performance lithium-ion batteries.
J Colloid Interface Sci
; 529: 265-272, 2018 Nov 01.
Article
em En
| MEDLINE
| ID: mdl-29908402
ABSTRACT
A mesoporous octahedral copper oxide@titania (CuO/TiO2) composites with core-shelled structure have been successfully fabricated via a facile and cost-effective approach, which involves two main steps:
the creation of homogeneous TiO2 shell onto the octahedral Cu-based metal-organic frameworks (MOFs) template and thermal decomposition of the template at controlled temperature in the air. The design of combining CuO with the TiO2 layer within a porous octahedra structure is beneficial to integrate the advantages of different components and address the severe volume change associated with pulverization issue that exists in most metal oxides-based electrodes. When assembled as an anode material for lithium-ion batteries, the as-fabricated mesoporous CuO/TiO2 octahedra can achieve outstanding electrochemical performance in terms of a high reversible capacity (692â¯mAhâ¯g-1 at 100â¯mAâ¯g-1 for over 200 cycles) and exceptional rate capability (441 and 387â¯mAâ¯hâ¯g-1 at 1600 and 3200â¯mAâ¯g-1, respectively).
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Bases de dados:
MEDLINE
Idioma:
En
Revista:
J Colloid Interface Sci
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Singapura