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Photochemical C-H Amination of Ethers and Geminal Difunctionalization Reactions in One Pot.
Hernández-Guerra, Daniel; Hlavacková, Anna; Pramthaisong, Chiranan; Vespoli, Ilaria; Pohl, Radek; Slanina, Tomás; Jahn, Ullrich.
Afiliação
  • Hernández-Guerra D; Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo námestí 2, 16610, Prague 6, Czech Republic.
  • Hlavacková A; Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo námestí 2, 16610, Prague 6, Czech Republic.
  • Pramthaisong C; Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo námestí 2, 16610, Prague 6, Czech Republic.
  • Vespoli I; Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo námestí 2, 16610, Prague 6, Czech Republic.
  • Pohl R; Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo námestí 2, 16610, Prague 6, Czech Republic.
  • Slanina T; Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo námestí 2, 16610, Prague 6, Czech Republic.
  • Jahn U; Institute of Organic Chemistry and Biochemistry of the Czech Academy of Sciences, Flemingovo námestí 2, 16610, Prague 6, Czech Republic.
Angew Chem Int Ed Engl ; 58(36): 12440-12445, 2019 09 02.
Article em En | MEDLINE | ID: mdl-31233670
ABSTRACT
A mild, atom-economic, and metal-free α-C-H amination of ethers using relatively stable nonafluorobutanesulfonyl (nonaflyl, Nf) azide as the aminating reagent to give N-sulfonyl hemiaminals is reported. This enables unprecedented C(sp3 ) difunctionalization reactions, leading to diverse functionalized amino group containing compounds starting from simple ethers in one pot.
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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Article País de afiliação: República Tcheca
Texto completo
Adicionar na Minha BVS
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XML
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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Article País de afiliação: República Tcheca