Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine.

Kiernicki, John J; Norwine, Emily E; Zeller, Matthias; Szymczak, Nathaniel K

Kiernicki, John J; Norwine, Emily E; Zeller, Matthias; Szymczak, Nathaniel K.

Afiliação

Kiernicki JJ; University of Michigan, 930 N. University, Ann Arbor, MI 48109, USA. nszym@umich.edu.
Norwine EE; University of Michigan, 930 N. University, Ann Arbor, MI 48109, USA. nszym@umich.edu.
Zeller M; H. C. Brown Laboratory, Purdue University, 560 Oval Dr, West Lafayette, IN 47907, USA.
Szymczak NK; University of Michigan, 930 N. University, Ann Arbor, MI 48109, USA. nszym@umich.edu.

Chem Commun (Camb) ; 55(79): 11896-11899, 2019 Oct 01.

Article em En | MEDLINE | ID: mdl-31528878

RESUMO

We present the preparation of a nitrogen-based bidentate ligand featuring an appended boron Lewis acid as well as its tetrahedral Fe2+ and Zn2+ complexes. These complexes act as platforms for hydrazine and hydroxylamine capture and reduction chemistry.

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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Estados Unidos

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