Secondary-Phase-Assisted Grain Boundary Migration in CuInSe_{2}.
Phys Rev Lett
; 124(9): 095702, 2020 Mar 06.
Article
em En
| MEDLINE
| ID: mdl-32202872
ABSTRACT
Significant structural evolution occurs during the deposition of CuInSe_{2} solar materials when the Cu content increases. We use in situ heating in a scanning transmission electron microscope to directly observe how grain boundaries migrate during heating, causing nondefected grains to consume highly defected grains. Cu substitutes for In in the near grain boundary regions, turning them into a Cu-Se phase topotactic with the CuInSe_{2} grain interiors. Together with density functional theory and molecular dynamics calculations, we reveal how this Cu-Se phase makes the grain boundaries highly mobile.
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Bases de dados:
MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Ano de publicação:
2020
Tipo de documento:
Article
País de afiliação:
Alemanha