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Copper-Catalyzed Perfluoroalkylation of Alkynyl Bromides and Terminal Alkynes.
Fan, Shilu; Zheng, Chenggong; Zheng, Kaiting; Li, Junlan; Liu, Yaomei; Yan, Fangpei; Xiao, Hua; Feng, Yi-Si; Zhu, Yuan-Yuan.
Afiliação
  • Fan S; School of Chemistry and Chemical Engineering, Hefei University of Technology, 193 Tunxi Road, Anhui 230000, China.
  • Zheng C; Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China.
  • Zheng K; School of Chemistry and Chemical Engineering, Hefei University of Technology, 193 Tunxi Road, Anhui 230000, China.
  • Li J; School of Chemistry and Chemical Engineering, Hefei University of Technology, 193 Tunxi Road, Anhui 230000, China.
  • Liu Y; School of Chemistry and Chemical Engineering, Hefei University of Technology, 193 Tunxi Road, Anhui 230000, China.
  • Yan F; School of Chemistry and Chemical Engineering, Hefei University of Technology, 193 Tunxi Road, Anhui 230000, China.
  • Xiao H; School of Chemistry and Chemical Engineering, Hefei University of Technology, 193 Tunxi Road, Anhui 230000, China.
  • Feng YS; School of Food and Biological Engineering, Hefei University of Technology, 193 Tunxi Road, Anhui 230000, China.
  • Zhu YY; School of Chemistry and Chemical Engineering, Hefei University of Technology, 193 Tunxi Road, Anhui 230000, China.
Org Lett ; 23(8): 3190-3194, 2021 Apr 16.
Article em En | MEDLINE | ID: mdl-33792322
A copper-catalyzed one-pot perfluoroalkylation of alkynyl bromides and terminal alkynes has been disclosed, and the corresponding perfluoroalkylated alkynes could be attained in good to excellent yields. The new straightforward transformation shows high efficiency (0.01-0.5 mol % catalyst loading), broad substrate scope, and remarkable functional group tolerance and provides a facile approach for useful application in life and material sciences.
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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: China
Texto completo
Adicionar na Minha BVS
Imprimir
XML
PubMed Links
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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2021 Tipo de documento: Article País de afiliação: China