Cobalt Bromide-Catalyzed Negishi-Type Cross-Coupling of Amides.

Dorval, Céline; Stetsiuk, Oleh; Gaillard, Sylvaine; Dubois, Elodie; Gosmini, Corinne; Danoun, Grégory

Dorval, Céline; Stetsiuk, Oleh; Gaillard, Sylvaine; Dubois, Elodie; Gosmini, Corinne; Danoun, Grégory.

Afiliação

Dorval C; LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.
Stetsiuk O; LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.
Gaillard S; LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.
Dubois E; LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.
Gosmini C; LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.
Danoun G; LCM, CNRS, Ecole polytechnique, Institut Polytechnique de Paris, 91120 Palaiseau, France.

Org Lett ; 24(14): 2778-2782, 2022 04 15.

Article em En | MEDLINE | ID: mdl-35380446

ABSTRACT

ABSTRACT

Herein, we describe a novel Negishi-type cross-coupling of amides employing only cobalt bromide salt as the catalyst. This original reaction is highly tolerant to various glutarimide amides as well as organozinc coupling partners. These conditions also allow the performance of the cross-coupling reaction in an eco-compatible solvent such as ethyl acetate on a large scale.

Assuntos

Amidas; Cobalto; Brometos; Catálise

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Texto completo: 1 Bases de dados: MEDLINE Assunto principal: Cobalto / Amidas Idioma: En Revista: Org Lett Assunto da revista: BIOQUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: França

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