Nanostructured Carbon-Doped BN for CO2 Capture Applications.
Nanomaterials (Basel)
; 13(17)2023 Aug 22.
Article
em En
| MEDLINE
| ID: mdl-37686897
ABSTRACT
Carbon-doped boron nitride (denoted by BN/C) was prepared through the pyrolysis at 1100 °C of a nanostructured mixture of an alkyl amine borane adduct and ammonia borane. The alkyl amine borane adduct acts as a soft template to obtain nanospheres. This bottom-up approach for the synthesis of nanostructured BN/C is relatively simple and compelling. It allows the structure obtained during the emulsion process to be kept. The final BN/C materials are microporous, with interconnected pores in the nanometer range (0.8 nm), a large specific surface area of up to 767 m2·g-1 and a pore volume of 0.32 cm3·g-1. The gas sorption studied with CO2 demonstrated an appealing uptake of 3.43 mmol·g-1 at 0 °C, a high CO2/N2 selectivity (21) and 99% recyclability after up to five adsorption-desorption cycles.
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Bases de dados:
MEDLINE
Idioma:
En
Revista:
Nanomaterials (Basel)
Ano de publicação:
2023
Tipo de documento:
Article
País de afiliação:
França