Removal of Pb (II) and Zn (II) in the mineral beneficiation wastewater by using cross-linked carboxymethyl starch-g-methacrylic acid as an effective flocculant.

ABSTRACT

The cross-linked carboxymethyl starch-g-methacrylic acid (CCMS-g-MAA) was prepared by using grafting and micro-cross-linking in the one-pot preparation process. CCMS-g-MAA presented high removal capacity of Pb (II) of 57.13 mg/g at pH = 4 and high removal capacity of Zn (II) of 51.41 mg/g at pH = 5 by using a sample dosage of 0.68 g/L. Characterization results of FTIR, TG, and XRD illustrate that methacrylic acid and sodium tri-metaphosphate were successfully introduced into the structure of carboxymethyl starch. SEM characterization presented that the sample particles were amorphous aggregates with surface voids, which was favorable for the adsorption of heavy metal ions from wastewater. Adsorption isotherm results indicated that Freundlich equation could be better used to describe the adsorption process of metal ions on CCMS-g-MAA. The adsorption kinetic results indicated that the pseudo-second-order model is more suitable to describe this removal process. XPS results indicated that metal ions interacted with functional groups on the surface of flocculant, especially carboxyl groups. The removal process may be purposed that metal ions were adsorbed by porous material, and then combined with surface functional groups of the flocculant via electrostatic interaction, chelation or ion exchange. Subsequently, metal ions were separated from the wastewater with flocs precipitated in the bottom of solution via bridging and patching. The obtained results illustrated that CCMS-g-MAA was an effective material for the treatment of wastewater containing polymetallic ions besides mineral beneficiation wastewater supported by its excellent regeneration.