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Preparations of trans- and cis-µ-1,2-Peroxodiiron(III) Complexes.
Kajita, Yuji; Kubo, Masaki; Arii, Hidekazu; Ishikawa, Shinya; Saito, Yamato; Wasada-Tsutsui, Yuko; Funahashi, Yasuhiro; Ozawa, Tomohiro; Masuda, Hideki.
Afiliação
  • Kajita Y; Department of Applied Chemistry, Graduate School of Engineering, Aichi Institute of Technology, 1247 Yachigusa, Yakusa-cho, Toyota 470-0392, Japan.
  • Kubo M; Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466-8555, Japan.
  • Arii H; Department of Education, Graduate School of Education, University of Miyazaki, Gakuenkibanadai-Nishi, Miyazaki 889-2192, Japan.
  • Ishikawa S; Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466-8555, Japan.
  • Saito Y; Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466-8555, Japan.
  • Wasada-Tsutsui Y; Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466-8555, Japan.
  • Funahashi Y; Department of Chemistry, Graduate School of Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-0043, Japan.
  • Ozawa T; Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso, Showa, Nagoya 466-8555, Japan.
  • Masuda H; Department of Applied Chemistry, Graduate School of Engineering, Aichi Institute of Technology, 1247 Yachigusa, Yakusa-cho, Toyota 470-0392, Japan.
Molecules ; 29(1)2023 Dec 29.
Article em En | MEDLINE | ID: mdl-38202788
ABSTRACT
The iron(II) complex with cis,cis-1,3,5-tris(benzylamino)cyclohexane (Bn3CY) (1) has been synthesized and characterized, which reacted with dioxygen to form the peroxo complex 2 in acetone at -60 °C. On the basis of spectroscopic measurements for 2, it was confirmed that the peroxo complex 2 has a trans-µ-1,2 fashion. Additionally, the peroxo complex 2 was reacted with benzoate anion as a bridging agent to give a peroxo complex 3. The results of resonance Raman and 1H-NMR studies supported that the peroxo complex 3 is a cis-µ-1,2-peroxodiiron(III) complex. These spectral features were interpreted by using DFT calculations.
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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: Molecules Assunto da revista: BIOLOGIA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Japão
Texto completo
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XML
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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: Molecules Assunto da revista: BIOLOGIA Ano de publicação: 2023 Tipo de documento: Article País de afiliação: Japão