Design of a Mesoionic Janus-type Dicarbene.

Leung, Jia Nuo; Huynh, Han Vinh

Leung, Jia Nuo; Huynh, Han Vinh.

Afiliação

Leung JN; Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science Drive 3, Singapore 117453, Republic of Singapore.
Huynh HV; Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science Drive 3, Singapore 117453, Republic of Singapore.

J Am Chem Soc ; 146(6): 3622-3626, 2024 Feb 14.

Article em En | MEDLINE | ID: mdl-38306245

ABSTRACT

ABSTRACT

A versatile synthetic strategy for the preparation of homo- and heterobimetallic complexes bearing an unprecedented mesoionic Janus-type diNHC is presented. Moreover, its electronic property is evaluated, and a preliminary catalytic application in the direct diarylation of 1-methylpyrrole is demonstrated.

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Texto completo: 1 Bases de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2024 Tipo de documento: Article