In Situ Preparation of Metallic Copper Nanosheets/Carbon Paper Sensitive Electrodes for Low-Potential Electrochemical Detection of Nitrite.
Sensors (Basel)
; 24(13)2024 Jun 29.
Article
em En
| MEDLINE
| ID: mdl-39001026
ABSTRACT
In the realm of electrochemical nitrite detection, the potent oxidizing nature of nitrite typically necessitates operation at high detection potentials. However, this study introduces a novel approach to address this challenge by developing a highly sensitive electrochemical sensor with a low reduction detection potential. Specifically, a copper metal nanosheet/carbon paper sensitive electrode (Cu/CP) was fabricated using a one-step electrodeposition method, leveraging the catalytic reduction properties of copper's high occupancy d-orbital. The Cu/CP sensor exhibited remarkable performance in nitrite detection, featuring a low detection potential of -0.05 V vs. Hg/HgO, a wide linear range of 10~1000 µM, an impressive detection limit of 0.079 µM (S/N = 3), and a high sensitivity of 2140 µA mM-1cm-2. These findings underscore the efficacy of electrochemical nitrite detection through catalytic reduction as a means to reduce the operational voltage of the sensor. By showcasing the successful implementation of this strategy, this work sets a valuable precedent for the advancement of electrochemical low-potential nitrite detection methodologies.
Texto completo:
1
Bases de dados:
MEDLINE
Idioma:
En
Revista:
Sensors (Basel)
Ano de publicação:
2024
Tipo de documento:
Article
País de afiliação:
China