1.
Chem Commun (Camb)
; 51(22): 4579-82, 2015 Mar 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-25683286
RESUMO
A variety of new dinuclear zinc catalysts was developed and tested for the copolymerization of cyclohexene oxide and carbon dioxide. Electron-withdrawing groups thereby led to unprecedented activities with turnover frequencies up to 155,000 h(-1). These are by far the highest polymerization rates ever reported for the copolymerization of cyclohexene oxide and CO2.