Dynamic Pluronic F127 Crosslinking Enhancement of Biopolymeric Nanocomposites for Piezo-Triboelectric Single-Hybrid Nanogenerators and Self-Powered Sensors.

Biomechanical and nanomechanical energy harvesting systems have gained a wealth of interest, resulting in a plethora of research into the development of biopolymeric-based devices as sustainable alternatives. Piezoelectric, triboelectric, and hybrid nanogenerator devices for electrical applications are engineered and fabricated using innovative, sustainable, facile-approach flexible composite films with high performance based on bacterial cellulose and BaTiO3 , intrinsically and structurally enhanced by Pluronic F127, a micellar cross-linker. The voltage and current outputs of the modified versions with multiwalled carbon nanotube as a conductivity enhancer and post-poling effect are 38 V and 2.8 µA cm-2 , respectively. The multiconnective devices' power density can approach 10 µW cm-2 . The rectified output power is capable of charging capacitors, driving light-emitting diode lights, powering a digital watch and interfacing with a commercial microcontroller board to operate as a piezoresistive force sensor switch as a proof of concept. Magnetoelectric studies show that the composites have the potential to be incorporated into magnetoelectric systems. The biopolymeric composites prove to be desirable candidates for multifunctional energy harvesters and electronic devices.

Photocatalytic degradation of dyes by novel electrospun nanofibers: A review.

Textile industry is a significant contributor of wastewater, which contains pollutants including dye and other chemical substances. The release of thousands of tons of dye used in textile processing and finishing into natural streams and aquatic bodies present dire harm to the environment. In response to environmental concerns, a number of research have been done using low-cost technology to produce absorbents that can remove dyes from water bodies. Distinct techniques such as adsorption, enzymatic and photocatalytic degradation, etc. have been employed to remove dyes. In the last few decades, photocatalysis, a simple and green strategy, has emerged as the most valuable and recent principle that deals with wastewater treatment, using uniquely fabricated nanomaterials. Among them, rapid and versatile electrospinning methods have been used for the construction of a large surface area, hierarchical and reusable nanofibers for environmental remediation. As a flexible and fast fabrication method, reviewing the use of electrospun photocatalytic nanofibers, influential parameters in electrospinning and their effectiveness in the generation of oxidizing agents are a promising platform for the fabrication of novel nanomaterials in photocatalytic degradation of dyes. This review discusses techniques for dye removal, electrospun nanofibers, their fabrication and application in photocatalysis; mechanism of photocatalytic degradation, and challenges and suggested remedies for electrospun nanofibers in photocatalysis.