Shoreline barriers may amplify coastal groundwater hazards with sea-level rise.

Subsurface barriers have been proposed to protect coastal aquifers from sea-level rise induced seawater intrusion, but the potential for groundwater emergence near subsurface barriers remains unknown. Here, we investigated how emergence changes groundwater flow conditions and influences the protective performance of subsurface barriers with sea-level rise. We tested the subterranean consequences of sea-level rise for cutoff walls and subsurface dams with cross-shore groundwater flow and salt transport models, investigating how barrier design, aquifer properties, and hydrological conditions control the potential for emergence, groundwater partitioning at the barrier, and seawater intrusion with sea-level rise. We find that most subsurface infrastructure cannot prevent seawater intrusion and emergence simultaneously. Subsurface dams spanning more than half of the aquifer thickness created emergence hazards and subsequent groundwater partitioning for all scenarios tested. Cutoff walls were less effective at reducing seawater intrusion for all opening sizes but could reduce the emergence potential compared to similarly sized subsurface dams. Our results demonstrate the challenging trade-offs in mitigating the coastal groundwater hazards of seawater intrusion and emergence with sea-level rise, where groundwater flooding inland of protective infrastructure would require combinations of subsurface impoundments and other mitigation techniques, such as pumping or drains.

The legacy and drivers of groundwater nutrients and pesticides in an agriculturally impacted Quaternary aquifer system.

Nutrient and pesticide pollution are among the major threats to groundwater quality in agriculturally impacted aquifers. Understanding their legacy effects and drivers are important to protect aquifers from exposures to contamination. However, the complexities of groundwater flowpaths make it difficult to predict the time-scales of groundwater flow and contaminant transport. To determine these controls of groundwater nutrient and pesticides in an aquifer system underlying an intensive agricultural area in the Great Barrier Reef catchment, Australia, we sampled tritium (3H) to estimate groundwater-age, nutrient and pesticide concentrations to investigate groundwater contamination, and nitrogen (ẟ15N-NO3-) and oxygen (ẟ18O-NO3-) isotopes to determine groundwater nitrate dynamics. We, then, constructed high-resolution 3D geological and groundwater flow models of the aquifer system to determine the role of the geologic heterogeneity on the observed nutrient and pesticide concentrations. Groundwater 3H derived ages, and nutrient and pesticide concentrations did not follow distinct spatial trends. ẟ15N-NO3- and ẟ18O-NO3- values indicated that nitrification and denitrification processes influenced nitrate dynamics in the aquifer system; however, they were not solely able to explain the entire 3D variability. The 3D geologic modelling identified possible preferential flowpaths and perched systems, which helped to explain the observed groundwater-age, nutrient and pesticide variabilities. Old-groundwater (~100-years) was found in shallow depths (<15 m) where perched systems were identified. In areas with preferential flowpaths, young-groundwater (⁓1-year) with significant nitrate (~12 mg-N/L) and pesticides (up to 315 ng/L) concentrations were detected at deeper depths (>25 m), below perched and locally confined systems. Downward increasing groundwater-age, and decreasing nutrient and pesticide concentrations were detected in the unconfined aquifer, while old-groundwater (~160-years) and lower nitrate (<3 mg-N/L) and pesticides (<2 ng/L) concentrations were detected in the confined systems. This study demonstrates the importance of understanding both the geology and the hydrogeology of an area before deploying monitoring studies and/or making conclusions from tritium, nutrient and pesticide data alone.