Shedding light on predicting and controlling emission chromaticity in multicomponent photoluminescent systems.

Predictable colour tuning in multicomponent photoluminescent (PL) systems is achieved using mixtures of simultaneously emitting organic molecules. By mitigating the potential for energy transfer through the control of concentration, the resulting emission chromaticity of five dichromic PL systems is approximated as a linear combination of the emitting components and their corresponding brightness (χ i , ϕ i , and I ex,i ). Despite being limited to dilute solutions (10-6 M), colour tuning within these systems was controlled by (1) varying the composition of the components and (2) exploiting the differences in the components' excitation intensities at common wavelengths. Using this approach, white light emission (WLE) was realized using a pre-determined mixture of red, green, and blue emitting organic molecules. Based on these results, materials and devices with built-in or programmable emission colour can be achieved, including highly sought-after WLE.

Microwave-assisted activation and modulator removal in zirconium MOFs for buffer-free CWA hydrolysis.

A novel, facile and efficient method was developed for the activation of acetic acid modulated zirconium MOFs. The protocol involves briefly heating the material in water using microwave irradiation. MOF-808, DUT-84 and UiO-66 were all activated in this manner to remove the modulator and organic solvent from the framework post synthesis, with retention of MOF integrity post activation. The degree of activation was characterised by the use of TGA and NMR. The catalytic activity of the activated MOFs and their non-activated counterparts was investigated for chemical warfare agent (CWA) hydrolysis. Upon activation, an increase in the rate of hydrolysis was observed in the degradation of CWA simulant dimethyl 4-nitrophenyl phosphate (DMNP). MOF-808 and DUT-84 were also screened as catalysts for the hydrolysis of the V-series agent VM, with remarkable half-lives obtained for MOF-808 in the absence of any buffers. Currently employed MOF activation procedures involve the use of additional organic solvents post synthesis; we believe this method to be ideally efficacious for the organic desolvation of zirconium MOFs and removing modulator additives.

Sensing a Bacillis anthracis biomarker with well-known OLED emitter EuTta3Phen.

Dipicolinic acid (DPA) is a distinctive biomarker for bacterial spores. Here, we present the successful demonstration of dramatic Switch-OFF sensing of DPA using an easily synthesised Eu(iii) phosphor applied primarily in light-emitting devices. The sensor in the presence of water and phosphate is also demonstrated to be effective.

Alkaline-earth phosphonate MOFs with reversible hydration-dependent fluorescence.

A new rigid tritopic phosphonic ligand, 2,4,6-tris(4-phosphonophenyl)pyridine (H6L), was synthesized and used to assemble isostructural barium (1) and strontium (2) phosphonate metal organic frameworks that exhibit fully reversible and selective water-dependent fluorescence red-shift at room temperature.