Crosslinking of Epoxidized Natural Rubber with Borax for Self-Healing and Self-Repairing Properties: pH Dependence.

Epoxidized natural rubber (ENR) crosslinked using borax, which exhibits self-healing and self-repairing properties, is successfully developed. The crosslink formation of ENR by using borax under neutral and alkaline conditions is investigated. Fourier transform infrared spectroscopy (FTIR) shows that the borate-ester bond is formed in ENR prepared under both neutral and alkaline conditions, whereas boron nuclear magnetic resonance (11 B-NMR) results exhibit that the ENR prepared under alkaline conditions more actively forms crosslink networks with borax. Moreover, the crosslink density and gel content increase significantly with the presence of borax in alkaline conditions. The crosslink density and gel content of ENR with 10 phr borax are higher by 155% and 36%, respectively, than those of neat ENR. Furthermore, the formation of the crosslinking ENR by borax enhances self-healing and self-repairing properties. The healing efficiency significantly increases from 1.09% to 85.90%, when ENR is developed under alkaline conditions with 30 phr borax. These results represent the first successful demonstration of the efficient use of borax as a crosslinker in ENR, which exhibits its promising self-healing and self-repairing properties under atmospheric conditions without the need for external stimuli. The ENR prepared in this work holds great promise for various self-healing rubber applications.

Development of water-resistant paper using chitosan and plant-based wax extracted from banana leaves.

On being exposed to water, cellulose paper swells and its mechanical properties become weak. In this study, natural wax with an average particle size of 12.3 µm extracted from banana leaves was mixed with chitosan to prepare coatings applied on paper surfaces. Chitosan efficiently dispersed banana leaf-extracted wax on paper surfaces. The mixed chitosan and wax coatings considerably influenced paper properties, including yellowness, whiteness, thickness, wettability, water absorption, oil sorption, and mechanical properties. The coating induced hydrophobicity in the paper, resulting in a significant increase in the water contact angle from 65.1 ± 7.7° (uncoated paper) to 123.2 ± 2.1°, and a decrease in water absorption by ⁓64 % to 52.6 ± 1.9 %. The coated paper demonstrated an oil sorption capacity of 212.2 ± 2.8 %, which was ⁓43 % greater than that of the uncoated paper (148.2 ± 5.5 %), and the tensile strength of the coated paper improved under wet conditions compared to the uncoated paper. Additionally, a separation of oil in water was observed for the chitosan/wax coated paper. Based on these promising results, the paper coated with chitosan and wax could be used for direct-contact packaging applications.

Property enhancement of epoxidized natural rubber nanocomposites with water hyacinth-extracted cellulose nanofibers.

Cellulose nanofibers (CNFs) have been widely used as reinforcement in various polymer matrices; however, limited studies of the use of CNFs in epoxidized natural rubber (ENR) have been reported. Here, we successfully prepared CNF-reinforced ENR nanocomposites with superior mechanical performance. CNFs were disintegrated from water hyacinth (Eichhornia crassipes) using high-pressure homogenization, and ENR nanocomposites with CNFs were fabricated by initial mixing and hot pressing. The crosslink densities of the nanocomposites with CNFs were higher than that of the neat ENR. Due to stronger interfacial interactions between the hydroxyl groups of the CNFs and the functional groups of the ENR, stress could be efficiently transferred from the ENR matrix to the stiff CNFs, resulting in a significant increase in the mechanical properties. Compared with those of the neat ENR, the tensile strength and Young's modulus of the ENR nanocomposites were improved by 80 and 39 %, respectively, with the incorporation of 2 parts per hundred rubber (phr) CNFs, whereas no loss in elongation at break was observed. The introduction of CNFs also improved the oil resistance of the nanocomposites. Therefore, CNFs could be the potential reinforcing agent in the ENR nanocomposites used in the various engineering applications of the rubber material.

Superabsorbent cellulose-based hydrogels cross-liked with borax.

Cellulose, the most abundant biopolymer on Earth, has been widely attracted owing to availability, intoxicity, and biodegradability. Environmentally friendly hydrogels were successfully prepared from water hyacinth-extracted cellulose using a dissolution approach with sodium hydroxide and urea, and sodium tetraborate decahydrate (borax) was used to generate cross-linking between hydroxyl groups of cellulose chains. The incorporation of borax could provide the superabsorbent feature into the cellulose hydrogels. The uncross-linked cellulose hydrogels had a swelling ratio of 325%, while the swelling ratio of the cross-linked hydrogels could achieve ~ 900%. With increasing borax concentrations, gel fraction of the cross-linked hydrogels increased considerably. Borax also formed char on cellulose surfaces and generated water with direct contact with flame, resulting in flame ignition and propagation delay. Moreover, the cross-linked cellulose-based hydrogels showed antibacterial activity for gram-positive bacteria (S. aureus). The superabsorbent cross-linked cellulose-based hydrogels prepared in this work could possibly be used for wound dressing, agricultural, and flame retardant coating applications.

Review of the recent developments in all-cellulose nanocomposites: Properties and applications.

Cellulose, the most abundant polysaccharide on Earth, has a number of desirable properties, including availability, biodegradability, low cost, and low toxicity and has been used in a variety of applications. Recently, all-cellulose composite materials have been made from a wide variety of cellulose sources, including wood and agricultural wastes, via impregnation or partial surface dissolution approaches utilizing a specific solvent. Due to the improved interfacial interactions between the cellulose matrix and cellulose reinforcement, all-cellulose composites exhibit superior mechanical properties when compared to biopolymers and petroleum-based polymers. The current article discusses the factors affecting the mechanical properties and interfacial bonding of all-cellulose composites. Additionally, the incorporation of inorganic nanoparticles is described to enhance the multi-functional properties of all-cellulose composites, such as their conductivity, permeability, and adsorption. Furthermore, this review summarizes the potential applications of all-cellulose composites in the following areas: composites, packaging, aerogels, hydrogels, fibers, tissue engineering, membranes, textiles, and coatings.