Iron-rich red mud and iron oxide-modified biochars: A comparative study on the removal of Cd(II) and influence of natural aging processes.

Red mud (RM) is a byproduct of various processes in the aluminum industry and has recently been utilized for synthesizing RM-modified biochar (RM/BC), which has attracted significant attention in terms of waste reutilization and cleaner production. However, there is a lack of comprehensive and comparative studies on RM/BC and the conventional iron-salt-modified biochar (Fe/BC). In this study, RM/BC and Fe/BC were synthesized and characterized, and the influence on environmental behaviors of these functional materials with natural soil aging treatment was analyzed. After aging, the adsorption capacity of Fe/BC and RM/BC for Cd(II) decreased by 20.76% and 18.03%, respectively. The batch adsorption experiments revealed that the main removal mechanisms of Fe/BC and RM/BC are co-precipitation, chemical reduction, surface complexation, ion exchange, and electrostatic attraction, etc. Furthermore, practical viability of RM/BC and Fe/BC was evaluated through leaching and regenerative experiments. These results can not only be used to evaluate the practicality of the BC fabricated from industrial byproducts but can also reveal the environmental behavior of these functional materials in practical applications.

Efficient and effective immobilization of tetracycline and copper from wastewater by zero-valent iron fabricated hydrochar derived from walnut peel.

Antibiotics and heavy metals often coexist as non-point-source contaminants in wastewater and their quite contrary physiochemical properties make their co-removal processes challenging. In this work, a bifunctional zero-valent iron-modified hydrochar derived from walnut peel (MWPHC) was synthesized, which was then applied for the simultaneous removal of tetracycline (TC) and Cu(II) from wastewater. Based on the characterizations, Fe0 species were successfully distributed on the surface of the walnut peel substrates. The TC and Cu(II) could be synergistically immobilized, and bridging effects were observed between them, and MWPHC exhibited excellent ability on the simultaneous removal of TC (qmax = 433.59 mg/g) and Cu(II) (qmax = 586.25 mg/g). Furthermore, the engineering feasibility of the MWPHC was evaluated using column and regeneration experiments. These results shed light on the tailored MWPHC as an environmental functional material for pollution control of co-existing antibiotic and heavy metal contaminants in agro-industrial wastewater.

Simultaneously Cationic and Anionic Dyes Elimination via Magnetic Hydrochar Prepared from Copper Slag and Pinewood Sawdust.

In practical wastewater, cationic and anionic dyes usually coexist, while synergistic removal of these pollutants is difficult due to their relatively opposite properties. In this work, copper slag (CS) modified hydrochar (CSHC) was designed as functional material by the one-pot method. Based on characterizations, the Fe species in CS can be converted to zero-valent iron and loaded onto a hydrochar substrate. The CSHC exhibited efficient removal rates for both cationic dyes (methylene blue, MB) and anionic dyes (methyl orange, MO), with a maximum capacity of 278.21 and 357.02 mg·g-1, respectively, which was significantly higher than that of unmodified ones. The surface interactions of MB and MO between CSHC were mimicked by the Langmuir model and the pseudo-second-order model. In addition, the magnetic properties of CSHC were also observed, and the good magnetic properties enabled the adsorbent to be quickly separated from the solution with the help of magnets. The adsorption mechanisms include pore filling, complexation, precipitation, and electrostatic attraction. Moreover, the recycling experiments demonstrated the potential regenerative performance of CSHC. All these results shed light on the co-removal of cationic and anionic contaminates via these industrial by-products derived from environmental remediation materials.

Hexavalent chromium elimination from wastewater by integrated micro-electrolysis composites synthesized from red mud and rice straw via a facile one-pot method.

The widely spread chromium (Cr) contamination is rising environmental concerns, while the reutilization of agro-industrial by-products are also urgently demanded due to their potential risks. In this study, we prepared the integrated micro-electrolysis composites (IMC) through a facile one-pot method with red mud and rice straw. The effects of components relatively mass ratios as well as pyrolysis temperature were analyzed. The XRD, XPS, SEM, FTIR, and various techniques proved the IMC was successfully synthesized, which was also used to analyze the reaction mechanisms. In this study, the dosage of IMC, pH, adsorption time, and temperature of adsorption processes were explored, in the adsorption experiment of Cr(VI), dosage of IMC was 2 g/L (pH 6, 25 °C, and 200 rpm) for isothermal, while the concentration and contact time were also varied. According to the batch experiments, IMC exhibited acceptable removal capacity (190.6 mg/g) on Cr(VI) and the efficiency reached 97.74%. The removal mechanisms of adsorbed Cr(VI) were mainly elaborated as chemical reduction, complexation, co-precipitation, and physical adherence. All these results shed light on the facile preparation and agro-industrial by-products recycled as engineering materials for the heavy metals decontamination in wastewater.

Selenite elimination via zero-valent iron modified biochar synthesized from tobacco straw and copper slag: Mechanisms and agro-industrial practicality.

Cost-effectively improving the performance of biochar is essential for its large-scale practical application. In this work, the agro-industrial by-products copper slag and tobacco straw were employed for the preparation of modified biochar (CSBC). The obtained CSBC exhibited satisfactory capacity on Se(IV) immobilization of 190.53 mg/g, with surface interactions determined by the monolayer and mainly chemisorption. The removal mechanisms included chemical reduction, electrostatic attraction, co-precipitation, and formation of complexations. Interestingly, the existence of Cu2Se structure after adsorption indicated the involvement of Cu species within Se(IV) elimination. Moreover, the industrial agricultural practicality of CSBC was evaluated by regeneration tests, economic assessment, and pot experiments. The results demonstrate that iron species-modified biochar prepared from two agro-industrial by-products is a promising and feasible candidate for selenite removal from wastewater.