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The unsatisfactory lithium-ion conductivity (σ) and limited mechanical strength of polymer solid electrolytes hinder their wide applications in solid-state lithium metal batteries (SSLMBs). Here, a thin piezoelectric polymer solid electrolyte integrating electromechanical coupling and ferroelectric polarization effects has been designed and prepared to achieve long-term stable cycling of SSLMBs. The ferroelectric Bi4Ti3O12 nanoparticle (BIT NPs) loaded poly(vinylidene fluoride-trifluoroethylene) (P(VDF-TrFE)) piezoelectric nanofibers (B-P NFs) membranes are introduced into the poly(ethylene oxide) (PEO) matrix, endowing the composite electrolyte with unique polarization and piezoelectric effects. The piezoelectric nanofiber membrane with a 3D network structure not only promotes the dissociation of lithium (Li) salts through the polarization effect but also cleverly utilizes the coupling effect of a mechanical stress-local electric field to achieve dynamic regulation of the Li electroplating process. Through the corresponding experimental tests and density functional theory calculations, the intrinsic mechanism of piezoelectric electrolytes improving σ and suppressing Li dendrites is fully revealed. The obtained piezoelectric electrolyte has achieved stable cycling of LiFePO4 batteries over 2000 cycles and has also shown good practical application potential in flexible pouch batteries.
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Lithium-sulfur batteries (LSBs) have the advantages of high theoretical specific capacity, excellent energy density, abundant elemental sulfur reserves. However, the LSBs is mainly limited by shuttling of lithium polysulfides (LiPSs), slow reaction kinetics of sulfur cathode. For solving the above problems, by developing high-performance battery separators, the reversible capacity, Coulombic efficiency (CE) and cycle life of LSBs can be effectively enhanced. Carbon-free based metal compounds are expected to be highly efficient separator modifiers for a new generation of high-performance LSBs by virtue of superior chemical adsorption capacity, strong catalytic properties and excellent lithophilicity to a certain extent. They can give play to the synergistic effect of their "adsorption-catalysis" sites to accelerate the redox kinetics of LiPSs, and their good lithophilicity can accelerate the Li+ transport kinetics, thus showing more remarkable electrochemical performances. However, a comprehensive summary of carbon-free metal compounds-modified separators for LSBs is still lacking. Here, this review systematically summarizes the researching progresses and performance characteristics of carbon-free-based metal compounds modified materials for separators of LSBs, and summarizes the corresponding mechanisms of using carbon-based separators to enhance the performance of LSBs. Finally, the review also looks forward to the prospects of LSBs using carbon-free metal compounds separators.
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Air pollutants and temperature are significant threats to public health, and the complex linkages between the environmental factors and their interactions harm respiratory diseases. This study is aimed to analyze the impact of air pollutants and meteorological factors on respiratory diseases and their synergistic effects in Dingxi, a city in northwestern China, from 2018 to 2020 using a generalized additive model (GAM). Relative risk (RR) was employed to quantitatively evaluate the temperature modification on the short-term effects of PM2.5 and O3 and the synergistic effects of air pollutants (PM2.5 and O3) and meteorological elements (temperature and relative humidity) on respiratory diseases. The results indicated that the RRs per inter-quatile range (IQR) rise in PM2.5 and O3 concentrations were (1.066, 95% CI: 1.009-1.127, lag2) and (1.037, 95% CI: 0.975-1.102, lag4) for respiratory diseases, respectively. Temperature stratification suggests that the influence of PM2.5 on respiratory diseases was significantly enhanced at low and moderate temperatures, and the risk of respiratory diseases caused by O3 was significantly increased at high temperatures. The synergy analysis demonstrated significant a synergistic effect of PM2.5 with low temperature and high relative humidity and an antagonistic effect of high relative humidity and O3 on respiratory diseases. The findings would provide a scientific basis for the impact of pollutants on respiratory diseases in Northwest China.
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Poluentes Atmosféricos , Umidade , Ozônio , Material Particulado , Temperatura , China/epidemiologia , Humanos , Doenças Respiratórias/epidemiologia , CidadesRESUMO
A 3D crimped sulfonated polyethersulfone-polyethylene oxide(C-SPES/PEO) nanofiber membrane and long-range lanthanum cobaltate(LaCoO3 ) nanowires are collectively doped into a PEO matrix to acquire a composite solid electrolyte (C-SPES-PEO-LaCoO3 ) for all-solid-state lithium metal batteries(ASSLMBs). The 3D crimped structure enables the fiber membrane to have a large porosity of 90%. Therefore, under the premise of strongly guaranteeing the mechanical properties of C-SPES-PEO-LaCoO3 , the ceramic nanowires conveniently penetrated into the 3D crimped SPES nanofiber without being blocked, which can facilitate fast ionic conductivity by forming 3D continuous organic-inorganic ion transport pathways. The as-prepared electrolyte delivers an excellent ionic conductivity of 2.5 × 10-4 S cm-1 at 30 °C. Density functional theory calculations indicate that the LaCoO3 nanowires and 3D crimped C-SPES/PEO fibers contribute to Li+ movement. Particularly, the LiFePO4 /C-SPES-PEO-LaCoO3 /Li and NMC811/C-SPES-PEO-LaCoO3 /Li pouch cell have a high initial discharge specific capacity of 156.8 mAh g-1 and a maximum value of 176.7 mAh g-1 , respectively. In addition, the universality of the penetration of C-SPES/PEO nanofibers to functional ceramic nanowires is also reflected by the stable cycling performance of ASSLMBs based on the electrolytes, in which the LaCoO3 nanowires are replaced with Gd-doped CeO2 nanowires. The work will provide a novel approach to high performance solid-state electrolytes.
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Developing highly efficient bi-functional noble-metal-free oxygen electrocatalysts with low-cost and scalable synthesis approach is challenging for zinc-air batteries (ZABs). Due to the flexible valence state of manganese, MnF2 is expected to provide efficient OER. However, its insulating properties may inhibit its OER process to a certain degree. Herein, during the process of converting the manganese source in the precursor of porous carbon nanofibers (PCNFs) to manganese fluoride, the manganese source is changed to manganese acetate, which allows PCNFs to grow a large number of hollow carbon nanorods (HCNRs). Meanwhile, manganese fluoride will transform from the aggregation state into uniformly dispersed MnF2 nanodots, thereby achieving highly efficient OER catalytic activity. Furthermore, the intrinsic ORR catalytic activity of the HCNRs/MnF2 @PCNFs can be enhanced due to the charge modulation effect of MnF2 nanodots inside HCNR. In addition, the HCNRs stretched toward the liquid electrolyte can increase the capture capacity of dissolved oxygen and protect the inner MnF2 , thereby enhancing the stability of HCNRs/MnF2 @PCNFs for the oxygen electrocatalytic process. MnF2 surface-modulated HCNRs can strongly enhance ORR activity, and the uniformly dispersed MnF2 can also provide higher OER activity. Thus, the prepared HCNRs/MnF2 @PCNFs obtain efficient bifunctional oxygen catalytic ability and high-performance rechargeable ZABs.
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Supramolecular hydrogels involved macrocycles have been explored widely in recent years, but it remains challenging to develop hydrogel based on solitary macrocycle with super gelation capability. Here, the construction of lantern[33 ]arene-based hydrogel with low critical gelation concentration (0.05 wt%), which can be used for efficient oil-water separation, is reported. The lantern[33 ]arenes self-assemble into hydrogen-bonded organic nanoribbons, which intertwine into entangled fibers to form hydrogel. This hydrogel which exhibits reversible pH-responsiveness characteristics can be coated on stainless-steel mesh by in situ sol-gel transformation. The resultant mesh exhibits excellent oil-water separation efficiency (>99%) and flux (>6 × 104 L m-2 h-1 ). This lantern[33 ]arene-based hydrogel not only sheds additional light on the gelation mechanisms for supramolecular hydrogels, but also extends the application of macrocycle-based hydrogels as functional interfacial materials.
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The effect of ambient temperature on health continues to draw more and more attention with the global warming. Bacillary dysentery (BD) is a major global environmental health issue and affected by temperature and other environmental variables. In the current study, we evaluated the effect of temperature on the incidence of BD from January 1st, 2008 to December 31st, 2011 in Jiayuguan, a temperate continental arid climate city in the Hexi Corridor of northwest China. A distributed lag non-linear model (DLNM) was performed to evaluate the lag effect of temperature on BD up to 30 days. Results showed the risk of BD increased with temperature significantly, especially after 8 °C. The maximum risk of BD was observed at extreme high temperature (29 °C). The effect of temperature on BD risk was significantly divided into short-term effect at lag 5 days and long-term effect at lag 30 days. Age ≤ 15 years were most affected by high temperature. The maximum cumulative risk for lag 30 days (25.8, 95% CIs: 11.8-50.1) was observed at 29 °C. Age ≤ 15 years and females showed short-term effect at lag 5 days and long-term effect at lag 30 days, while age > 15 years and males showed acute short-term effect at lag 0 and light long-term effect at lag 16 days.
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Disenteria Bacilar , Masculino , Feminino , Humanos , Adolescente , Temperatura , Incidência , Disenteria Bacilar/epidemiologia , Temperatura Alta , China/epidemiologiaRESUMO
Lithium-sulfur batteries (LSBs) are attracting much attention due to their high theoretical energy density and are considered to be the predominant competitors for next-generation energy storage systems. The practical commercial application of LSBs is mainly hindered by the severe "shuttle effect" of the lithium polysulfides (LiPSs) and the serious damage of lithium dendrites. Various carbon materials with different characteristics have played an important role in overcoming the above-mentioned problems. Carbon spheres (CSs) are extensively explored to enhance the performance of LSBs owing to their superior structures. The review presents the state-of-the-art advances of CSs for advanced high-energy LSBs, including their preparation strategies and applications in inhibiting the "shuttle effect" of the LiPSs and protecting lithium anodes. The unique restriction effect of CSs on LiPSs is explained from three working mechanisms: physical confinement, chemical interaction, and catalytic conversion. From the perspective of interfacial engineering and 3D structure designing, the protective effect of CSs on the lithium anode is also analyzed. Not only does this review article contain a summary of CSs in LSBs, but also future directions and prospects are discussed. The systematic discussions and suggested directions can enlighten thoughts in the reasonable design of CSs for LSBs in near future.
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Carbono , Lítio , Carbono/química , Fontes de Energia Elétrica , Eletrodos , Lítio/química , EnxofreRESUMO
Breast cancer is a highly heterogeneous disease. Subtyping the disease and identifying the genomic features driving these subtypes are critical for precision oncology for breast cancer. This study focuses on developing a new computational approach for breast cancer subtyping. We proposed to use Bayesian tensor factorization (BTF) to integrate multi-omics data of breast cancer, which include expression profiles of RNA-sequencing, copy number variation, and DNA methylation measured on 762 breast cancer patients from The Cancer Genome Atlas. We applied a consensus clustering approach to identify breast cancer subtypes using the factorized latent features by BTF. Subtype-specific survival patterns of the breast cancer patients were evaluated using Kaplan-Meier (KM) estimators. The proposed approach was compared with other state-of-the-art approaches for cancer subtyping. The BTF-subtyping analysis identified 17 optimized latent components, which were used to reveal six major breast cancer subtypes. Out of all different approaches, only the proposed approach showed distinct survival patterns (p < 0.05). Statistical tests also showed that the identified clusters have statistically significant distributions. Our results showed that the proposed approach is a promising strategy to efficiently use publicly available multi-omics data to identify breast cancer subtypes.
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Neoplasias da Mama , Teorema de Bayes , Neoplasias da Mama/genética , Variações do Número de Cópias de DNA , Feminino , Genômica , Humanos , Medicina de PrecisãoRESUMO
Epidemiological studies have reported significant associations between weather situations and health. Cardiovascular disease is a serious chronic non-communicable disease which causes mortality and morbidity, bringing large economic burden to patients' families. This study explored the relationship between cardiovascular disease (CVD) and weather conditions in Changchun, northeast China. The frequency distributions of 13 main circulation weather types (CWTs) were analyzed, and a comparison between air mass classification and hospital admissions was performed for various groups using an admission index (AI). The results indicated that women had a lower risk of CVD than men did. The risk of CVD for older people (aged ≥ 65 years) was lower than that for young people (aged < 65 years). Younger men had the highest risk. The risks of CVD were higher in all groups (i.e., men, women, older, and younger) under southwesterly (SW) and northerly (N) CWTs and were lowest under the anticyclone (A) CWT. The risk of CVD among men was higher than that for women under these CWTs. N type circulation is characterized by cold, dry weather and was most closely associated with an increased incidence of CVD. The most significant effect of N type circulation on AI was observed with a delay of 2 days. SW type circulation is characterized by humid, hot weather and was the CWT that was second most closely associated with an increased incidence of CVD, with a peak in AI on the day that SW type circulation occurred. The results of this study could be provided to local health authorities as scientific guidelines for controlling and preventing CVD in Changchun, China.
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Poluição do Ar , Doenças Cardiovasculares , Adolescente , Idoso , Poluição do Ar/análise , Doenças Cardiovasculares/epidemiologia , China/epidemiologia , Feminino , Hospitalização , Hospitais , Humanos , Masculino , Tempo (Meteorologia)RESUMO
Recently, particulate matter pollution has been worsening, which has been affecting the asthma visits in children. In this study, we assessed the short-term effects of PM10 and PM2.5 on asthma visits in children in Shanghai, China from January 1, 2009 and December 31, 2010, using a generalized additive model. We controlled the confounding factors, such as long-term trends, week day effect, and weather elements. The lag effects of different age subgroups (≤ 2 yr, 3-5 yr, and 6-18 yr subgroups) were performed. The results showed significant effects of PM10 and PM2.5 on asthma visits in children, though the seasonal lags varied for the three age subgroups. In general, the effect of PM2.5 on asthma visits in children was stronger and more acute than that of PM10. PM2.5 showed the highest relative risk of 1.192 at lag 0 day in summer; and PM10 showed the highest relative risk of 1.073 at lag 3 day in autumn. Overall, particulate matter pollution showed a greater effect on relatively younger children. In particular, the ≤ 2 yr subgroup showed the highest seasonal relative risk of PM10. Especially, seasonal relative risk of PM10 in autumn for the ≤ 2 yr subgroup was much higher than that for the other two subgroups. The 3-5 yr and 6-18 yr subgroups showed the highest seasonal relative risk of PM2.5 in summer and winter, respectively. But the pediatric visits data we obtained cannot reflect the true prevalence of asthma and multiple visits. Thus, selection bias may exist in our analysis.
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Poluentes Atmosféricos , Poluição do Ar , Asma , Poluentes Atmosféricos/efeitos adversos , Poluentes Atmosféricos/análise , Poluição do Ar/efeitos adversos , Poluição do Ar/análise , Asma/epidemiologia , Asma/etiologia , Criança , China/epidemiologia , Hospitais , Humanos , Material Particulado/efeitos adversos , Material Particulado/análiseRESUMO
Epidemiological studies have suggested that particulate matter (PM) pollution seriously affects human health, particularly it is closely associated with respiratory diseases. The aim of this study is to quantitatively evaluate the effect of PMs (PM10 and PM2.5) on emergency room (ER) visits for respiratory diseases in Lanzhou, a valley basin city in northwest China. Based on the data of the ER visits, daily concentration of particulate matters and daily meteorological elements from January 1, 2013, to July 31, 2017, we used a generalized additive model (GAM) of time series to evaluate the exposure-response relationship between PMs and respiratory ER visits. Seasonal modified effects of PM2.5 and PM10 on different age and gender groups were also performed. Results showed that the highest incidence of respiratory diseases occurred in winter. Respiratory ER visits for the total were significantly associated with PM2.5 (at lag 0 day) and PM10 (at lag 3 days), with relative risks (RRs) of 1.042 (95%CI: 1.036 -1.047) and 1.013 (95%CI: 1.011-1.016), respectively. Effects of PM pollutants on respiratory diseases are different among different age and gender groups. Children under 15 years and the elders over 60 years were the most sensitive to PM pollution, and males were more sensitive than females. The results obtained in the current study would provide a scientific evidence for local government to make policy decision for prevention of respiratory diseases.
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Poluentes Atmosféricos , Poluição do Ar , Idoso , Poluentes Atmosféricos/análise , Poluentes Atmosféricos/toxicidade , Poluição do Ar/efeitos adversos , Poluição do Ar/análise , Criança , China/epidemiologia , Serviço Hospitalar de Emergência , Exposição Ambiental/análise , Feminino , Humanos , Masculino , Material Particulado/análise , Material Particulado/toxicidadeRESUMO
All-solid-state electrolytes have received extensive attention due to their excellent safety and good electrochemical performance. However, due to the harsh conditions of the preparation process, the commercial production of all-solid-state electrolytes remains a challenge. The outbreak of the novel coronavirus pneumonia (COVID-19) has caused great inconvenience to people, while also allowing soft, lightweight and mass-producible non-woven fabrics in masks come into sight. Here, a polymer/polymer solid composite electrolyte is obtained by introducing the polyamide 6 (PA6) microfiber non-woven fabric into PEO polymer through the hot-pressing method. The addition of the PA6 non-woven fabric with lithium-philic properties can not only reduce the crystallinity of the polymer, but also provide more functional transmission sites and then promote the migration of lithium ions at the molecular level. Moreover, due to the sufficient mechanical strength and flexibility of the PA6 non-woven fabric, the composite electrolyte shows excellent inhibition ability of lithium dendrite growth and high electrochemical stability. The novel design concept of introducing low-cost and large-scale production of non-woven fabrics into all-solid-state composite electrolytes to develop high-performance lithium metal batteries is attractive, and can also be broadened to the combination of different types of polymers to meet the needs of various batteries.
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Discovery of novel two-dimensional (2D) materials is of fundamental importance but remains challenging. In this work, we design a simple and facile bottom-up approach to fabricate a new family of 2D acetate-based light lanthanide fluoride nanomaterials (F-Ln, Ln = La, Ce, Pr, Nd) at room temperature and atmosphere pressure, for the first time. Various characterization techniques confirm that as-synthesized F-Ln exhibit an ultrathin morphology with thickness up to 1.45 nm and lateral dimensions up to several hundred nanometers. Microstructure analysis demonstrates that F-Ln are a series of defect-rich 2D nanomaterials, which consist of nanocrystals with sub-10 nm domains. Structure characterization of F-Ce, a typical example, infers that BN-like F-Ce one-atom-layers sandwiched by intercalated acetate anions stack alternately along [001] direction to form nanocrystal building blocks of F-Ce. The study of growth mechanism suggests that three procedures are involved in the formation of F-Ce: hydrolysis reaction of cerium(III) acetate, structure transformation induced by fluorine ions, and assembly process guided by acetate anions. The as-prepared nanosheets show excellent stability with respect to environment stimuli such as air, heat, solvent, and high-energy electron beam. This study enriches the library of 2D materials and paves the way for future application of such 2D materials in areas such as catalysis, adsorption, separation, and energy storage/conversion.
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A novel hierarchical nanofibrous membrane was demonstrated via in situ self-assembly of 1,3:2,4-dibenzylidene-d-sorbitol (DBS) supramolecular fibrils in solution-blown polyacrylonitrile (PAN) nanofibers. The formed DBS fibrils were interconnected into networks and anchored onto the PAN nanofibers, which decreased the pore sizes and enhanced the mechanical properties, the filtration efficiency, and particularly the flux.
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Zhi zhu xiang (ZZX for short) is the root and rhizome of Valeriana jatamansi Jones, which is a Traditional Chinese Medicine (TCM) used to treat various mood disorders for more than 2000 years, especially anxiety. The aim of the present work was to identify the bioactive chemical markers in Zhi zhu xiang improving anxiety in rats by a fingerprint-efficacy study. More specifically, the chemical fingerprint of ZZX samples collected from 10 different regions was determined by High Performance Liquid Chromatography (HPLC) and the similarity analyses were calculated based on 10 common characteristic peaks. The anti-anxiety effect of ZZX on empty bottle stimulated rats was examined through the Open Field Test (OFT) and the Elevated Plus Maze Test (EPM). Then we measured the concentration of CRF, ACTH, and CORT in rat's plasma by the enzyme-linked immune sorbent assay (ELISA) kit, while the concentration of monoamine and metabolites (NE, DA, DOPAC, HVA, 5-HT, 5-HIAA) in the rat's cerebral cortex and hippocampus was analysed by HPLC coupled with an Electrochemical Detector. At last, the fingerprint-efficacy study between chemical fingerprint and anti-anxiety effect of ZZX was accomplished by partial least squares regression (PLSR). As a result, we screened out four compounds (hesperidin, isochlorogenic acid A, isochlorogenic acid B and isochlorogenic acid C) as the bioactive chemical markers for the anti-anxiety effect of ZZX. The fingerprint-efficacy study we established might provide a feasible way and some elicitation for the identification of the bioactive chemical markers for TCM.
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Ansiedade/tratamento farmacológico , Ácido Clorogênico/administração & dosagem , Medicamentos de Ervas Chinesas/administração & dosagem , Hesperidina/administração & dosagem , Valeriana/química , Hormônio Adrenocorticotrópico/sangue , Animais , Ansiedade/sangue , Ansiedade/etiologia , Ácido Clorogênico/análogos & derivados , Ácido Clorogênico/química , Ácido Clorogênico/farmacologia , Cromatografia Líquida de Alta Pressão , Modelos Animais de Doenças , Medicamentos de Ervas Chinesas/química , Medicamentos de Ervas Chinesas/farmacologia , Hesperidina/química , Hesperidina/farmacologia , Análise dos Mínimos Quadrados , Masculino , Neuropeptídeos/sangue , Raízes de Plantas/química , Ratos , Receptores de Hormônio Liberador da Corticotropina/sangue , Rizoma/químicaRESUMO
The complex microenvironment of diabetic wounds often hinders the healing process, ultimately leading to the formation of diabetic foot ulcers and even death. Dual monitoring and treatment of wounds can significantly reduce the incidence of such cases. Herein, a multifunctional Janus membrane (3D chitosan sponge-ZE/polycaprolactone nanofibers-ZP) was developed by incorporating the zinc metal-organic framework, europium metal-organic framework, and phenol red into nanofibers for diabetic wound monitoring and treatment. The directional water transport capacity of the resulting Janus membrane allows for unidirectional and irreversible drainage of wound exudate, and the multifunctional Janus membrane creates up to a 99% antibacterial environment, both of which can treat wounds. Moreover, the pH (5-8) and H2O2 (0.00-0.80 µM) levels of the wound can be monitored using the color-changing property of phenol red and the fluorescence characteristic of Eu-MOF on the obtained membrane, respectively. The healing stages of the wound can also be monitored by analyzing the RGB values of the targeted membrane images. This design can more accurately reflect the wound state and treat the wound to reduce bacterial infection and accelerate wound healing, which has been demonstrated in in vivo experiments. The results provide an important basis for early intervention in diabetic patients.
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Antibacterianos , Estruturas Metalorgânicas , Nanofibras , Cicatrização , Cicatrização/efeitos dos fármacos , Animais , Nanofibras/química , Nanofibras/uso terapêutico , Estruturas Metalorgânicas/química , Estruturas Metalorgânicas/farmacologia , Antibacterianos/química , Antibacterianos/farmacologia , Poliésteres/química , Quitosana/química , Zinco/química , Fenolsulfonaftaleína/química , Európio/química , Camundongos , Humanos , Membranas Artificiais , Peróxido de Hidrogênio/química , Diabetes Mellitus Experimental/tratamento farmacológico , Pé Diabético/tratamento farmacológico , Pé Diabético/patologia , Staphylococcus aureus/efeitos dos fármacosRESUMO
In this work, carboxylated and amination modified cellulose nanofibrils (CNFs) were fabricated via the TEMPO catalytic oxidation system and diethylenetriamine, and collagen composite aerogels were fabricated through a simple self-assembly pretreatment and directional freeze-drying technology. Morphology analysis showed that the collagen composite aerogels had distinct layered-oriented double network structures after the self-assembly pretreatment. The intermolecular interactions between the collagen fibrils and functionalized CNFs (fCNFs) on the structures and properties of the composite aerogels were also examined through various characterization techniques. Water contact angle tests demonstrated the pH-responsive characteristics of the collagen/fCNF composite aerogels. Using 5-fluorouracil as the model drug, the pH-response mechanism was revealed. These results indicated that the collagen/fCNF composite aerogels exhibited excellent pH-responsive drug release capacities. Therefore, these pH-responsive collagen composite aerogels might have potential applications in industrial production in the biomedical, drug delivery, and tissue engineering fields.
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Nanofibras , Géis/química , Nanofibras/química , Celulose/química , Sistemas de Liberação de Medicamentos , Colágeno , Concentração de Íons de HidrogênioRESUMO
Air pollution poses a major threat to both the environment and public health. The air quality index (AQI), aggregate AQI, new health risk-based air quality index (NHAQI), and NHAQI-WHO were employed to quantitatively evaluate the characterization of air pollution and the associated health risk in Gansu Province before (P-I) and after (P-II) COVID-19 pandemic. The results indicated that AQI system undervalued the comprehensive health risk impact of the six criteria pollutants compared with the other three indices. The stringent lockdown measures contributed to a considerable reduction in SO2, CO, PM2.5, NO2 and PM10; these concentrations were 43.4%, 34.6%, 21.4%, 17.4%, and 14.2% lower in P-II than P-I, respectively. But the concentration of O3 had no obvious improvement. The higher sandstorm frequency in P-II led to no significant decrease in the ERtotal and even resulted in an increase in the average ERtotal in cities located in northwestern Gansu from 0.78% in P-I to 1.0% in P-II. The cumulative distribution of NHAQI-based population-weighted exposure revealed that 24% of the total population was still exposed to light pollution in spring during P-II, while the air quality in other three seasons had significant improvements and all people were under healthy air quality level.
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Poluentes Atmosféricos , Poluição do Ar , COVID-19 , Material Particulado , China/epidemiologia , Humanos , Poluição do Ar/efeitos adversos , Poluição do Ar/análise , COVID-19/epidemiologia , Poluentes Atmosféricos/análise , Poluentes Atmosféricos/efeitos adversos , Material Particulado/análise , Material Particulado/efeitos adversos , SARS-CoV-2/isolamento & purificação , Monitoramento Ambiental/métodos , Exposição Ambiental/efeitos adversos , Saúde Pública , Dióxido de Enxofre/análise , Dióxido de Enxofre/efeitos adversos , Medição de Risco , Ozônio/análiseRESUMO
Solid-state lithium metal batteries (SSLMBs) have gained significant attention in energy storage research due to their high energy density and significantly improved safety. But there are still certain problems with lithium dendrite growth, interface stability, and room-temperature practicality. Nature continually inspires human development and intricate design strategies to achieve optimal structural applications. Innovative solid-state electrolytes (SSEs), inspired by diverse natural species, have demonstrated exceptional physical, chemical, and mechanical properties. This review provides an overview of typical bionic-structured materials in SSEs, particularly those mimicking plant and animal structures, with a focus on their latest advancements in applications of solid-state lithium metal batteries. Commencing from plant structures encompassing roots, trunks, leaves, flowers, fruits, and cellular levels, the detailed influence of biomimetic strategies on SSE design and electrochemical performance are presented in this review. Subsequently, the recent progress of animal-inspired nanostructures in SSEs is summarized, including layered structures, surface morphologies, and interface compatibility in both two-dimensional (2D) and three-dimensional (3D) aspects. Finally, we also evaluate the current challenges and provide a concise outlook on future research directions. We anticipate that the review will provide useful information for future reference regarding the design of bionic-structured materials in SSEs.