Mass balance of complementary metasomatic processes using isocon analysis.

This study develops a method to estimate the redistribution of elements during several associated metasomatic processes simultaneously involved in the formation of a geological complex. The method is based on classical mass balancing using isocon analysis. The proposed approach is applicable if geological prerequisites indicate that (a) the metasomatic rocks inherited some components (x, y, etc.) from one of the earlier rocks of the studied complex; (b) these components have been transported by a fluid; and (c) this saturated fluid has produced several varieties of metasomatic rocks rich in components x, y, etc. In the case of the specified background, the proposed method estimates the mass proportions between the source rock and the varieties of the resulting metasomatic rocks. We present the geological profile of the processes to which the proposed method is applicable, the mathematical model of the method, examples of the application and interpretation of the results, and geological criteria to verify the obtained model results. In brief,•This study introduces a method for calculating the mass proportions between the source rock and metasomatic rocks formed from the material remobilized from the source rock;•The paper considers the applicability limits of the method, exemplifies the interpretation of the results, and shows the methods for monitoring the correctness of these results.

Removing Pollutants from Sewage Waters with Ground Apricot Kernel Shell Material.

For the first time, a comprehensive review of the literature data on the use of apricot (Prunus armeniaca) biomass components as a sorption material for the treatment of wastewater and environmental water from various pollutants is carried out in the present study. In addition to a comprehensive analysis of contemporary studies, the current work carried out its own microstructural and energy dispersive studies. It shows that apricot kernel shell is a promising raw material for obtaining sorption materials that can be used to extract various pollutants from aqueous media. The parameters of sorption interaction are presented, at which the highest rate of removal of pollutants was achieved. It is shown that the sorption capacity of apricot biomass components can be increased by modifying it with various chemical reagents, as well as other physical and physicochemical methods. We reveal that most publications consider the use of the latter as a raw material for the production of activated carbons. It is established that the surface area and total pore space of activated carbons from apricot kernel shells depend on the modes of carbonization and activation. It is shown that activated carbons are effective adsorbents for removing various pollutants (metal ions, dyes, oil and oil products) from aqueous media. It was found that the adsorption isotherms of pollutants in most cases are best described by the Langmuir and Freundlich models, and the process kinetics is most often described by the pseudo-second-order model. The possibility of improving the sorption characteristics of apricot biomass during chemical or physicochemical treatment is also shown.

Technogenic Fiber Wastes for Optimizing Concrete.

A promising method of obtaining mineral fiber fillers for dry building mixtures is the processing of waste that comes from the production of technogenic fibrous materials (TFM). The novelty of the work lies in the fact that, for the first time, basalt production wastes were studied not only as reinforcing components, but also as binder ones involved in concrete structure formation. The purpose of the article is to study the physical and mechanical properties of waste technogenic fibrous materials as additives for optimizing the composition of raw concrete mixes. To assess the possibility of using wastes from the complex processing of TFM that were ground for 5 and 10 min as an active mineral additive to concrete, their chemical, mineralogical, and granulometric compositions, as well as the microstructure and physical and mechanical characteristics of the created concretes, were studied. It is established that the grinding of TFM for 10 min leads to the grinding of not only fibers, but also pellets, the fragments of which are noticeable in the total mass of the substance. The presence of quartz in the amorphous phase of TFM makes it possible to synthesize low-basic calcium silicate hydrates in a targeted manner. At 90 days age, at 10-20% of the content of TFM, the strength indicators increase (above 40 MPa), and at 30% of the additive content, they approach the values of the control composition without additives (above 35 MPa). For all ages, the ratio of flexural and compressive strengths is at the level of 0.2, which characterizes a high reinforcing effect. Analysis of the results suggests the possibility of using waste milled for 10 min as an active mineral additive, as well as to give better formability to the mixture and its micro-reinforcement to obtain fiber-reinforced concrete.