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1.
J Am Chem Soc ; 127(20): 7264-5, 2005 May 25.
Artigo em Inglês | MEDLINE | ID: mdl-15898746

RESUMO

The need for wear- and scratch-resistant materials drives the quest for new superhard materials. In this work, we apply two design parameters to identify ultra-incompressible, superhard materials-high valence electron density and high bond covalency. Our first example of such a material is OsB2. The bulk modulus of OsB2 was measured using in situ high-pressure X-ray diffraction and was determined to be in the range of 365-395 GPa. While this value is slightly less than that of the bulk modulus of diamond, due to the anisotropic crystal structure of OsB2, the axis compressibility in the orthorhombic c-direction is less than the axis compressibility found in diamond. OsB2 also scratches the surface of a sapphire window, indicating that the hardness of OsB2 exceeds 2000 kg/mm2.

2.
Science ; 308(5726): 1268-9, 2005 May 27.
Artigo em Inglês | MEDLINE | ID: mdl-15919983
3.
Science ; 306(5699): 1134-5; author reply 1134-5, 2004 Nov 12.
Artigo em Inglês | MEDLINE | ID: mdl-15539587
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