Polarization-multiplexed full-space metasurface simultaneously merging with an ultrawide-angle antireflection and a large-angle retroreflection.

Multifunctional electromagnetic (EM) metasurfaces are capable of manipulating electromagnetic waves with kaleidoscopic functions flexibly, which will significantly enhance integration and applications of electronic systems. However, most known design schemes only realize the reflection or transmission functions under a specific angle range, which wastes the other half EM space and restricts wider applications of multifunctional metadevices. Herein, an encouraging strategy of broadband and wide-angle EM wavefronts generator is proposed to produce two independent functions, i.e., antireflections for transverse electric (TE) waves and retroreflection for transverse magnetic (TM) waves, which utilizes band-stop and bandpass responses of the metasurface, respectively. As a feasibility verification of this methodology, a three-layer cascaded metasurface, composed of anisotropic crossbar structures patterned on the two surfaces of a dielectric substrate with sandwiched orthogonal metal-gratings, is designed, fabricated, and measured. Both the simulated and experimental results are in good accordance with theoretical analyses. This full-space metasurface opens up a new route to multifunctional metasurfaces and will further promote engineering applications of metasurfaces.

Tailoring permittivity using metasurface: a facile way of enhancing extreme-angle transmissions for both TE- and TM-polarizations.

The transmission of electromagnetic (EM) waves through a dielectric plate will be decreased significantly when the incident angle becomes extremely large, regardless of transverse electric (TE)- or transverse magnetic (TM)- polarization. In this regard, we propose a facile way of tailoring the permittivity of the dielectric material using metasurface to enhance the transmissions of both TE- and TM-polarized waves under extremely large incidence angles. Due to parallel or antiparallel electric fields induced by the metasurface, the net electric susceptibility is altered, and hence the effective permittivity can be tailored to improve the impedance matching on the two air-dielectric interfaces, which enhances the wave transmissions significantly under extreme incident angles. As an example, we apply this method to a typical ceramic-matrix composite (CMC) plate. By incorporating orthogonal meta-gratings into the CMC plate, its effective permittivity is reduced for the TE-polarized waves but increased for the TM-polarized waves under the extreme incidence angle, which can reduce the impedance for the TE-polarization and increase the Brewster angle for the TM-polarization. Therefore, the impedance matchings for both TE- and TM-polarizations are improved simultaneously and dual-polarized transmission enhancements are achieved under the extreme angles. Here, the transmission responses have been numerically and investigated using the finite-difference-time-domain (FDTD) method. A proof-of-principle prototype is designed, fabricated, and measured to verify this method. Both numerical simulations and measurement results show that the prototype can operate under extremely large incidence angles θi∈[75°,85°] with significant transmission enhancement for both TE- and TM-polarizations compared to the pure dielectric plate. This work provides a facile way to enhance the transmissions under extreme angles and can be readily extended to terahertz and optical frequencies.

Transmission enhancement of a half-wave wall under extreme angles by synergy of double lorentz resonances.

The a half-wave wall is usually adopted as the transparent window for electromagnetic (EM) waves ranging from microwave to optical regimes. Due to the interference nature, the bandwidth of the half-wave wall is usually quite narrow, especially under extreme angles for TE-polarized waves. It is usually contradictory to expand the bandwidth and to keep high transmission. To overcome this contradiction, we propose to extend the transmission bandwidth of half-wave walls under extreme angles by introducing Lorentz-type resonances using metasurfaces. The impedance of the half-wave wall is firstly analyzed. To improve the impedance matching, the impedance below and above the half-wave frequency should be increased. To this end, metallic wires and I-shaped structures are incorporated into the half-wave wall as the mid-layer. Due to the Lorentz-type resonance of the metallic wire, effective permittivity below the half-wave frequency can be reduced while that above the half-wave frequency can be increased due to Lorentz-type resonance of the I-shaped structures, both under large incident angles. In this way, the impedance matching, and thus the transmission, can be improved within an extended band. A proof-of-principle prototype was designed, fabricated, and measured to verify this strategy. Both simulated and measured results show that the prototype can operate in 14.0-19.0GHZ under incident angle [70°, 85°] with significant transmission enhancement for TE-polarized waves. This work provides an effective method of enhancing the transmission of EM waves and may find applications in radomes, IR windows, and others.

Quasi-omnidirectional retroreflective metagrating for TE-polarized waves based on wave-vector reversions.

Structuring elements of gratings brings more freedom in manipulating diffraction waves, e.g., retroreflection using diffraction orders other than the 0th order. Most retroreflective metagratings (RMs) can achieve retroreflection only under one particular direction, limiting their applications. In this paper, we propose a quasi-omnidirectional RM based on wave-vector reversion for TE-polarized waves. The metagrating element is composed of four rotationally-symmetric sub-elements, which is composed of one probe and two directors on its two sides. The substrate-air-metal layer can reverse kz while directors can reverse kx. Therefore, the wave-vector k of reflected waves can be completely reversed by the sub-element, providing necessary momentum for retroreflection. The -2nd diffraction order of the metagrating is tailored to channel out waves with reversed k, leading to retroreflection. Due to the element's four-fold rotational symmetry, retroreflection can be achieved along four directions, covering all of the four quarters of azimuth angle. We demonstrate prototypes in Ku band, and the average backscattering enhancement compared with a metal plane with the same area (SAMP) along the four directions reaches up to 31.3 dB with incident angle 50.0° at 15.0 GHz. Both simulated and measured results verify our design. This work provides another perspective on retroreflection and may find applications in retroreflective functional devices.

Extremely angle-stable transparent window for TE-polarized waves empowered by anisotropic metasurfaces.

Impedance mismatch generally exists upon interfaces between different media. This is especially true for TE-polarized waves with large incident angles since there is no Brewster effect. As a result, high-efficiency transmission can only be guaranteed within limited incident angle range. It is desirable that transparent windows possess robust angle-stability. In this work, we propose a strategy of realizing transparent windows with extreme angle-stability using anisotropic metasurfaces. Different from traditional isotropic materials, anisotropic metasurfaces require specific three-dimensional permittivity and permeability parameters. Theoretical formulas are derived to realize a highly efficient transmission response without angular dispersion. To validate our design concept, a two-layer cascaded electromagnetic anti-reflector is designed, and it exhibits a characteristic impedance matching for nearly all incidence angles under TE-polarization illumination. As a proof-of-concept, a prototype of extremely angle-stable transparent window is fabricated and measured. Compared with the pure dielectric plate, the reflection coefficients are on average reduced by 40% at 13.5 GHz for TE-polarized waves from 0° to 80°. Therefore, we think, anisotropic cascaded electromagnetic transparent windows are capable of tailoring the electromagnetic parameter tensors as desired, and provide more adjustable degrees of freedom for manipulating electromagnetic wavefronts, which might open up a promising way for electromagnetic antireflection and find applications in radomes, IR windows and others.

Multifunctional full-space metasurface controlled by frequency, polarization and incidence angle.

Multifunctional metasurfaces have exhibited considerable abilities of manipulating electromagnetic (EM) waves, especially in full-space manipulation. However, most works are implemented with functions controlled by polarization or frequency and seldom involve the incidence angle. Herein, we propose a multifunctional full-space metasurface controlled by frequency, polarization and incidence angle. A meta-atom is firstly designed. When EM waves illumine normally in the C-band, it possesses the characteristic of asymmetric transmission with high-efficient polarization conversion. In the Ku-band, both x- and y-polarized EM waves along both sides will be reflected and achieve broadband and high-efficient cross-polarization conversion. Also, when illumined obliquely, both sides can achieve efficient retroreflection at a certain frequency. As a proof of concept, a metasurface consisting of the above meta-atoms is configured as a dual orbital angular momentum (OAM) vortex beam generator and different beam deflector when illumined normally. Meanwhile, it acts as a multi-channel retroreflector when illumined obliquely. Both the simulated and measured results show excellent performances. Our findings provide a new degree of freedom to design multifunctional metasurfaces that can further promote applications.

Effect of Prestirring Time on Carbon Removal from Coal Fly Ash in the Flotation Technology.

Coal fly ash (CFA) is one of the industrial byproducts of burning coal for energy production and has unburned carbon, which negatively affects its full potential use. The flotation technology can be effective in separating unburned carbon from CFA, and the prestirring time is crucial for the ideal initial conditions during the flotation process. To find the suitable prestirring time, eight prestirring times, including 0, 1, 2, 3, 4, 5, 6, and 7 min, were selected in this paper, followed by flotation of CFA after prestirring. Parameters such as loss on ignition (LOI), the removal rate of unburned carbon (RUC), contact angle, and particle size volume fraction were used to assess the effect of prestirring time on flotation results. The results showed that the prestirring time significantly affects the CFA flotation performance. As the prestirring time increased, the LOI of CFA first decreased and then increased, and the contact angle showed the opposite trend. Besides, the prestirring time of over 2 min positively affected the fineness of the tailings. Overall, the prestirring time of 3 min had the most significant carbon removal effect, obtaining an LOI of tailings of 0.96%, a yield of 74.56%, an RUC of 72.70%, and a volume fraction less than 45 µm of 36.65%. This study provides theoretical support for improving stirring efficiency and saving flotation costs in industrial applications and is conducive to the recycling of CFA resources.

Low-temperature synthesis of colloidal few-layer WTe2 nanostructures for electrochemical hydrogen evolution.

High-quality transition metal tellurides, especially for WTe2, have been demonstrated to be necessarily synthesized under close environments and high temperatures, which are restricted by the low formation Gibbs free energy, thus limiting the electrochemical reaction mechanism and application studies. Here, we report a low-temperature colloidal synthesis of few-layer WTe2 nanostructures with lateral sizes around hundreds of nanometers, which could be tuned the aggregation state to obtain the nanoflowers or nanosheets by using different surfactant agents. The crystal phase and chemical composition of WTe2 nanostructures were analyzed by combining the characterization of X-ray diffraction and high-resolution transmission electron microscopy imaging and elements mapping. The as-synthesized WTe2 nanostructures and its hybrid catalysts were found to show an excellent HER performance with low overpotential and small Tafel slope. The carbon-based WTe2-GO and WTe2-CNT hybrid catalysts also have been synthesized by the similar strategy to study the electrochemical interface. The energy diagram and microreactor devices have been used to reveal the interface contribution to electrochemical performance, which shows the identical performance results with as-synthesized WTe2-carbon hybrid catalysts. These results summarize the interface design principle for semimetallic or metallic catalysts and also confirm the possible electrochemical applications of two-dimensional transition metal tellurides.

The Impact of COVID-19 on Tourist Satisfaction with B&B in Zhejiang, China: An Importance-Performance Analysis.

After the outbreak of COVID-19 (especially in the stage of tourism recovery), the bed and breakfast (B&B) tourism industry faced big challenges in improving its health strategies. B&Bs are very important for the tourism industry in China and many other countries. However, few studies have studied the impact of B&Bs, under COVID-19, on tourism in China. Our paper is among one of the first studies to investigate the impact of COVID-19 on tourist satisfaction with B&Bs in China. The work/travel restrictions started from 20 January 2020, and work/after travel resumed from 20 February 2020 in Zhejiang, China. Data were collected from 588 tourists (who experienced B&Bs in Zhejiang, China) from a WeChat online survey, from 1 March to 15 March 2020. The current study attempted to fill the gap by studying the changing tourist satisfaction levels with B&Bs before/after COVID-19. Moreover, some suggestions are given to the B&B industry for tourism resumption after COVID-19 by an importance-performance analysis (IPA).