Comparison of 3R4F cigarette smoke and IQOS heated tobacco product aerosol emissions.

In this study, the smoke from a 3R4F research cigarette and the aerosol generated by the Heated Tobacco Product IQOS, also referred to as the Tobacco Heating System (THS) 2.2 in the literature, were compared. The objective was to characterize the gas and suspended particulate matter compositions in the mainstream smoke from a combusted 3R4F cigarette and in the aerosol generated by IQOS during use. The results indicated that the determined aerosol emissions from IQOS were notably lower than in the cigarette smoke under a Health Canada Intense puffing regimen. As an interesting detail in this study, the maximum nicotine concentrations within a puff were practically the same in both the 3R4F smoke and the IQOS aerosol, but the average concentration was lower for the IQOS aerosol. For both products, water constituted a significant proportion of the particulate matter, although it was substantially higher in the IQOS aerosol. Furthermore, combustion-related solid particles observed in the 3R4F smoke contained elements such as carbon, oxygen, potassium, calcium, and silicon. In contrast, IQOS aerosol particulate matter was composed of semi-volatile organic constituents with some minor traces of oxygen and silicon. The particulate matter found in the IQOS aerosol was volatile, which was especially noticeable when exposed to the electron beam of the scanning electron microscope (SEM) and Transmission Electron Microscope (TEM).

Emission measurements of heavy metals with the European standard reference methods EN 14385 and EN 13211-observations from interlaboratory comparison (ILC) measurements performed at waste-to-energy plant in Finland.

This study presents the heavy metal results obtained during Finnish interlaboratory comparison (ILC) measurements made during 2019. The aim of this measurement campaign was to verify the skills of accredited emission measurement teams and also to evaluate the challenges that stack testing teams face in the future when emission levels decrease. ILCs have been organized in Finland since the 1970s. ILCs provide an important platform for stack testing teams so that they can verify their measurement skills and also for the dissemination of knowledge. The knowledge about the measurement standards and their requirements has improved among stack testing teams during past years in Finland. As emission levels get lower, they still need to pay more attention to some quality assurance procedures, e.g. to method and field blanks. Based on the observations of this ILC for heavy metals it can be noted that the challenges that stack testing teams face are related to the fact that no guidance is given in the standard reference methods EN 13211 and EN 14385 for example on the calculation of measurement uncertainties and how results below limit of quantification should be taken into account. These reference methods were suitable for their purpose at the time they were validated. However, emission levels are now more stringent and it is challenging to measure them with acceptable uncertainty criteria. As a consequence, there is a clear need for harmonized approaches in Europe for consistent implementation of standards and regulations. Key issues where guidance should be provided include realistic measurement uncertainties at low concentration levels, reporting low concentrations and guidance on how measurement uncertainties should be taken into account when the results are used for compliance assessment. The overall aim is to ensure that even with low emission levels, the emission measurement results would be transparent and robust throughout the EU. Implications: Interlaboratory comparison measurements between stack testing teams are the most important tool to verify the quality of the measurements. Participation in an appropriate ILC is often mandatory to successfully achieve accreditation under ISO/IEC 17025. Such campaigns also provide an efficient platform for dissemination of knowledge. In addition, ILCs can be used to clarify the challenges that teams nowadays face when measuring low emission levels, thus creating important information for the revision work of standards.

SO2 emission measurement with the European standard reference method, EN 14791, and alternative methods - observations from laboratory and field studies.

EN 14791 is a European Standard Reference method for the measurement of SO2 in emissions. This standard is based on a wet-chemical method in which SO2 present in flue gases is absorbed into an absorption solution containing hydrogen peroxide, and analyzed as sulfates after sampling. This study presents the results obtained when three portable automated measuring systems (P-AMS), based on Fourier-transform infrared (FTIR) spectroscopy, non-dispersive infrared (NDIR) and ultraviolet-fluorescence (UV) techniques, were compared to the Standard Reference Method for SO2 (EN 14791) in order to verify whether they could be used as alternative methods (AM) to EN 14791. In the case of FTIR, the measurements were performed from hot and wet gas, without any conditioning. UV-fluorescence analyzers were equipped with dilution probes and one NDIR applied a permeation dryer, whereas the other had a chiller. Tests were carried out at concentration ranges from 0 to 200 mg/m3(n) and from 0 to 800 mg/m3(n) for testing of equivalency according to CEN/TS 14793 using a test bench. Equivalency test criteria were met for all tested P-AMS except for NDIR at the lower range. The SO2 results measured with NDIR and the chiller were lower compared to the set-up with NDIR and permeation. This was most probably due to the chiller causing absorption of SO2 in the condensate. Tests were also carried out at field conditions, measuring the SO2 emissions from a boiler combusting mainly bark. The same phenomena were observed in these tests as during the test bench study, i.e. the measurement set-up with NDIR and the chiller gave the lowest results. These data demonstrated that the tested alternative methods (FTIR, UV-fluorescence, and NDIR) could be used instead of the standard reference method EN 14791, thus providing real-time calibration of automated measuring systems. It must however be emphasized that when measuring water-soluble gases, such as SO2, the choice of suitable conditioning technique is critical in order to minimize losses of the studied component in the condensate. Implications: Portable automated measuring systems (P-AMS) provide real-time information about emissions and their concentrations, thus offering significant advantages compared to wet-chemical methods. This study presents results which can be used as a validation protocol to show that the tested P-AMS techniques (FTIR, NDIR, UV-fluorescence) could be used instead of EN 14791 (CEN 2017a) as alternative methods (AM), when paying attention to the selection of an appropriate conditioning technique.

Emissions from a fast-pyrolysis bio-oil fired boiler: Comparison of health-related characteristics of emissions from bio-oil, fossil oil and wood.

There is currently great interest in replacing fossil-oil with renewable fuels in energy production. Fast pyrolysis bio-oil (FPBO) made of lignocellulosic biomass is one such alternative to replace fossil oil, such as heavy fuel oil (HFO), in energy boilers. However, it is not known how this fuel change will alter the quantity and quality of emissions affecting human health. In this work, particulate emissions from a real-scale commercially operated FPBO boiler plant are characterized, including extensive physico-chemical and toxicological analyses. These are then compared to emission characteristics of heavy fuel-oil and wood fired boilers. Finally, the effects of the fuel choice on the emissions, their potential health effects and the requirements for flue gas cleaning in small-to medium-sized boiler units are discussed. The total suspended particulate matter and fine particulate matter (PM1) concentrations in FPBO boiler flue gases before filtration were higher than in HFO boilers and lower or on a level similar to wood-fired grate boilers. FPBO particles consisted mainly of ash species and contained less polycyclic aromatic hydrocarbons (PAH) and heavy metals than had previously been measured from HFO combustion. This feature was clearly reflected in the toxicological properties of FPBO particle emissions, which showed less acute toxicity effects on the cell line than HFO combustion particles. The electrostatic precipitator used in the boiler plant efficiently removed flue gas particles of all sizes. Only minor differences in the toxicological properties of particles upstream and downstream of the electrostatic precipitator were observed, when the same particulate mass from both situations was given to the cells.