RESUMO
In the proposed study, an efficient method for a carbon dot@ß-cyclodextrin (C-dot@ß-CD)-based fluorescent probe was developed for the analyses of catechol (CC) and hydroquinone (HQ) at trace levels in water samples. The properties of C-dot@ß-CD nanocomposites were characterized by Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The sensing behaviors of C-dot@ß-CD toward CC and HQ were investigated by fluorescence spectroscopy. Based on the host-guest chemistry between C-dot@ß-CD and phenolic compounds, which can quench C-dot@ß-CD fluorescence, the prepared C-dot@ß-CD nanocomposites could be used for the sensitive and selective detection of CC or HQ across a wide linear range (0.1 to 10 µM) with detection limits of 47.9 and 20.2 nM, respectively. These results showed that the synthesized C-dot@ß-CD nanocomposite exhibited strong fluorescence and high degree of water solubility and thus, it is suitable for use as a nanoprobe for detecting CC or HQ in real water samples.