Fabrication of novel CuFe2O4/MXene hierarchical heterostructures for enhanced photocatalytic degradation of sulfonamides under visible light.

The overuse of sulfonamides, causing serious pollution of water bodies, has drawn great attention from society. To address these problems, a novel CuFe2O4/MXene (CFO/Ti3C2) heterojunction photocatalyst was used to photodegrade the antibiotic sulfamethazine (SMZ, a typical pollutant) under visible light, and the synergy and coupling function of the two components in the heterojunction system were analyzed. With the aid of time-resolved photoluminescence (TRPL) and transient surface photovoltage (TPV) spectra, the carrier lifetimes and kinetic behaviors were studied, revealing that the lifetime of photoinduced carriers was prolonged by loading Ti3C2, inhibiting the reorganization of photogenerated electron holes. More importantly, the organic intermediates and mineralization degree were identified by high-performance liquid chromatography (HPLC)-mass spectrometry (MS) and total organic carbon (TOC) techniques. The results show that the breaking of SN bonds, the oxidation of aniline and deamination were dominated by the attack of •OH. This work shows a new model for the degradation mechanism of SMZ over CFO/MXene heterostructures.

Removal of Fluorine from Wet-Process Phosphoric Acid Using a Solvent Extraction Technique with Tributyl Phosphate and Silicon Oil.

The deep removal of fluorine from wet-process phosphoric acid is currently a very serious issue. In this paper, an efficient liquid-liquid separation method based on a bubble membrane was developed to solve this problem. Tributyl phosphate (TBP) and silicon oil (SIO) were used as the organic phase. The effects of the component proportion in the organic phase (TBP/SIO v/v), organic to aqueous phase ratio (O/A), pH, temperature, and reaction time on the extraction ratio were investigated. The extraction ratio of fluorine was 98.4% when using only one stage with the following conditions: 90 °C, pH -0.46, volume ratio (TBP/SIO v/v) of 7:3, phase ratio (O/A) of 1:5, stirring speed of 200 rpm, and reaction time of 50 min. Fourier-transform infrared spectroscopy and inverted fluorescence microscopy were used to investigate the reaction mechanism and reaction kinetics. In addition, the scrubbing and stripping process was investigated. When a 2 mol/L sodium hydroxide solution ([NaOH]) was used as the stripping agent with a phase ratio (O/A) of 1:10, a stirring speed of 200 rpm, and a reaction time of 30 min, a maximum stripping ratio of 90.1% was obtained.

Fabrication of Ag/AgBr/Ag3VO4 composites with high visible light photocatalytic performance.

Herein, Ag/AgBr/Ag3VO4 composites were synthesized by a simple continuous precipitation method. The obtained composites were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDS), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy and photoluminescence spectroscopy (PL). Photocatalytic performance of the composites was assessed by the degradation of methyl orange (MO) and tetracycline hydrochloride (TC) under visible light, and the effects of different nominal mass ratios of AgBr and Ag3VO4 on the photocatalytic activity were investigated. The results showed that after 20 min of visible light irradiation (λ > 420 nm), the removal rate of MO in the presence of a 5 : 1 sample reached 98.6%. The EIS and photocurrent results demonstrated that the enhancement of the visible light photocatalytic activity was attributed to the efficient electron-hole pair separation. In addition, the scavenging reactions conducted via the addition of different scavengers confirmed that h+ and ·O2- were the main active species in the reaction. The present study offers potential for the degradation of contaminants.