CeO2 nanospheres incorporated with Bi2MoO6/g-C3N4 enhanced photocatalysis towards environmental pollutant Rhodamine B removal.

We have adopted a novel CeO2/Bi2MoO6/g-C3N4-based ternary nanocomposite that was synthesized via hydrothermal technique. The physiochemical characterization of as-prepared samples was examined through various analytical techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscopy (FE-SEM), transmission electron microscopy TEM, photoluminescent spectra (PL), X-ray photoelectron spectroscopy (XPS), Brunauer-Emmett-Teller (BET), and ultraviolet diffuse reflectance spectroscopy (UV-DRS) technique. In addition, the photocatalytic performance was carried out by degradation of Rhodamine B dye under visible light irradiation using this nanocatalyst. The ternary nanocomposite achieved 94% of the degradation efficiency within 100 min which is higher than the pristine and binary composites under the predetermined condition pH = 7, Rhodamine B dye = 5 mg/L, and catalyst concentration = 150 mg/L. The experimental synergetic effect of CeO2/Bi2MoO6/g-C3N4 ternary nanocomposite has been ascribed to the interfacial charge carrier migration between CeO2, Bi2MoO6, and g-C3N4. The optical absorption range of CeO2/Bi2MoO6/g-C3N4 ternary nanocomposite was enhanced, and the band gap was reduced up to 2.2 eV. In addition, scavenger trapping experiment proves that the super oxide anions (O2-.) and photogenerated holes are the major active species. The reusability and stability experiment proved the CeO2/Bi2MoO6/g-C3N4 ternary nanocomposite keeps good durability during the photocatalytic degradation process after the five successive cycles. Furthermore, based on the results, the charge carrier transfer photocatalytic mechanism was also discussed. This CeO2/Bi2MoO6/g-C3N4 ternary nanocomposite may offer the cheapest material and extend the great opportunity for clean and environmental remediation approach under the visible light irradiation.

Pioneering superior efficiency in Methylene blue and Rhodamine b dye degradation under solar light irradiation using CeO2/Co3O4/g-C3N4 ternary photocatalysts.

In this research work, we have successfully synthesized the CeO2/Co3O4/g-C3N4 ternary nanocomposite for hydrothermal method for photocatalytic applications. The synthesized nanocomposites were characterized using X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, Field emission scanning electron microscopy (FE-SEM), Transmission electron microscopy TEM, Photoluminescent spectra (PL), X-ray photoelectron spectroscopy (XPS), Brunauer- Emmett-Teller (BET) and Ultraviolet diffuse reflectance spectroscopy (UV-DRS) technique. As per the optical spectroscopic investigations CeO2/Co3O4/g-C3N4 ternary nanocomposite exhibited the high optical absorption range and its band gap is reduced from 2.95 eV to1.83 eV. The PL spectra showed the lowered emission peak intensity of ternary nanocomposite which is revealed that the better charge separation and slow recombination of electron hole pairs. The highest photocatalytic degradation efficiency of CeO2/Co3O4/g-C3N4 ternary nanocomposite showed 93 % and 86 % towards the pollutant methylene blue and Rhodamine B. Moreover, photodegradation of the pollutants followed pseudo-first order kinetics with a very high-rate constant of 0.02211 min-1 and 0.017756 min-1. Additionally, the ternary nano catalyst was delivered the remarkable stability performance even after five cycles. This research may provide a low-cost approach for synthesized visible light responsive catalysts for use in environmental remediation applications.

An efficient optical properties of Sn doped ZnO/CdS based solar light driven nanocomposites for enhanced photocatalytic degradation applications.

Metal sulfide - semiconductor nanocomposites synthesized with well-defined tin metal, exhibited the wide bandgap, the absorptions are limited to the UV-vis region for reduction of Reactive Blue 160 (RB 160) under solar light irradiation. The prepared samples were characterized using optoelectronic techniques. Conveniently, a wider range of wavelengths and physical properties can be enabled by doping these metal oxide nanoparticles. Whereas the photoreduction of RB 160 is unambiguously associated within charge separation and transmission progression from the excited Sn doped ZnO/CdS. Furthermore, Photocatalytic degradation efficiency for the Sn doped ZnO/CdS composites still reliant on the excitation strength, indicating the several electrons and protons were precise as a result of charge separation and transmission in prepared catalyst. Sn doped ZnO/CdS composites shows 94% Photocatalytic degradation efficiency within 120 min under sunlight irradiation. This photocatalytic nanocomposites may find capable applications in solar cells to power stretchable and also in wearable electronics.