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RSC Adv ; 13(34): 23558-23569, 2023 Aug 04.
Artigo em Inglês | MEDLINE | ID: mdl-37555094

RESUMO

A comprehensive investigation of the gas sensing potential of BeS monolayer has been conducted using DFT calculations. Twelve common pollutant gases: NH3, NO2, NO, CO, CO2, CH4, H2, O2, N2, H2S, H2O and SO2, have been studied. Our analysis reveals defect states in the band structure near the Fermi level and strong hybridization between gas molecule orbitals and the BeS monolayer. We observe higher adsorption energies for NH3 and CO compared to other popular gas sensing materials. The optical properties of CO2 and NO2 adsorbed on the BeS monolayer show increased reflectivity and absorption coefficient in the UV and far infrared region. Tensile strain has minimal impact on adsorption energy, while biaxial compressive strains enhance the gas sensing capability of the BeS monolayer. The application of an electric field offers control over gas adsorption and desorption. We propose the BeS monolayer as a promising candidate for future gas molecule sensing applications due to its high adsorption energy, rapid recovery time, and distinct optical properties.

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