Dimensional stability and mechanical properties of extruded-compression biopolymer composites made from selected Nigerian grown wood species at varying proportions.

250 µm particle size of wood and polyethylene (PE) materials were compounded at mixing proportions of 60/40, 70/30, and 80/20 (with an increase in polymer to decrease in wood content) and extruded using a single screw extruder at a temperature range of 110-135 °C. The particles of Gmelina Arborea, Tectona grandis, Cordia milleni, and Nauclea diderichii with recycled Polyethylene were compounded and compressed at 175 N/mm to produce biopolymer composites. The biopolymer composites were subjected to dimensional stability test at 24 h of the water soak method and the ability to withstand load-bearing capacity was investigated. The outcome of the results shows that extruded-compressive biopolymer composites had values ranging from 0.06-1.43 g/cm3, 0.38-3.41%, and 0.82-6.85% for observed density, water absorption, and thickness swelling at 24 h of a water soak test. The mechanical properties values ranged from 0.28 Nmm-2-21.35 Nmm-2 and 0.44-550.06 Nmm-2 for flexural modulus and strength; and 191.43 Nmm-2-1857.24 Nmm-2 and 0.35 Nmm-2-243.75 Nmm-2 for tensile modulus and strength respectively. It was observed that moisture uptake and strength displayed by the composites vary accordingly in values obtained for wood species at different mixing proportions. As observed that the more polyethylene content is compounded to wood, the better its dimensional stability, and flexural and tensile properties. The wood particles of Cordia milleni compounded at a proportion of 60 to 40 (polyethylene/wood) performed best in dimensional stability and load-bearing capacity. This study confirmed the effect of methods on wood species and recycled PE for manufacturing wood polymer-based composite for both indoor and outdoor applications.

Ternary and quaternary blends as partial replacement of cement to produce hollow sandcrete blocks.

Hollow sandcrete blocks constitute more than 90% of residential building construction in developing countries especially in West Africa. Over-reliance on dredged river sands and conventional ordinary Portland cement (OPC) contributes to environmental degradation and post-construction problems such as swelling and shrinkage-induced cracks prevalent in construction projects. The study investigates potential utilization of locally available materials such as laterite, calcite and calcined clay as ternary and quaternary blends to replace cement and quarry dust as 100% replacement of river sand with the aid of Taguchi-Response surface methodology approach. Optimum ternary blend of 24% calcined clay +1% calcite +75% OPC is recommended to achieve volume stability, higher compressive strength and higher flexural load capacity. Alternatively, ternary blends of 24% calcite +4% calcined clay +72% OPC can also be utilized. The improved mechanical properties were attributed to the Na- and Ca-rich aluminosilicates provided by the blended cements. Successful utilization of ternary and quaternary blended cements to produce stronger, durable and eco-friendly sandcrete blocks depends on utilization of high binder-to-aggregate ratio, optimal combination of the constituents, appropriate water-cement ratio and curing/production method. Partial and 100% replacement of river sand with granite dust is possible and contributes to reduction of environmental problems caused by river dredging as well as cleaner, ecofriendly construction. Ternary and quaternary blended cements is recommended to avert post-construction problems such as swelling and shrinkage-induced cracks prevalent in construction projects.