1.
J Am Chem Soc
; 127(42): 14554-5, 2005 Oct 26.
Artigo
em Inglês
| MEDLINE
| ID: mdl-16231891
RESUMO
An uncommon synergism in the concerted action of OH- and PR3 toward the simple Ru(II) complex Ru(CO)3Cl2(thf) allows a highly efficient reduction of the metal in ethanol or acetonitrile solution at 0 degrees C, with selective production of the corresponding Roper's-type Ru(0) complexes Ru(CO)2(PR3)3 in high yields within 10 min.