Chicken albumen-based whispering gallery mode microlasers.

Microlasers based on biomaterials have attracted enormous interest because of their promising potential for future applications in medical treatments, bio-tracking, and biosensing. In this work, we demonstrate chicken albumen as a novel and excellent low-cost biomaterial for a laser cavity. By using a simple but effective emulsion process, rhodamine B-doped chicken albumen microspheres with various diameters ranging from 20 µm to 100 µm can be fabricated. Under optical pulse excitation, these microspheres emit lasing emission. The lasing mechanism is investigated and ascribed to the whispering gallery mode (WGM). A threshold of 23.2 µJ mm-2 and a high Q-factor of approximately 2400 are obtained from an 82 µm-diameter microsphere. Size-dependent lasing characteristics are also examined, and the result shows good agreement with the WGM theory. Interestingly, these microsphere biolasers can operate in aqueous and biological environments such as water and human blood serum, which makes them a promising candidate for laser-based biosensing and biological applications.

Protein-based microsphere biolasers fabricated by dehydration.

Biolasers made of biological materials have attracted considerable research attention due to their biocompatibility and biodegradability, and have the potential for biosensing and biointegration. However, the current fabrication methods of biolasers suffer from several limitations, such as complicated processing, time-consuming and environmentally unfriendly nature. In this study, a novel approach with green processes for fabricating solid-state microsphere biolasers has been demonstrated. By dehydration via a modified Microglassification™ technology, dye-doped bovine serum albumin (BSA) droplets could be quickly (less than 10 minutes) and easily changed into solid microspheres with diameters ranging from 10 µm to 150 µm. The size of the microspheres could be effectively controlled by changing either the concentration of the BSA solution or the diameter of the initial droplets. The fabricated microspheres could act as efficient microlasers under an optical pulse excitation. A lasing threshold of 7.8 µJ mm-2 and a quality (Q) factor of about 1700 to 3100 were obtained. The size dependence of lasing characteristics was investigated, and the results showed a good agreement with whispering gallery mode (WGM) theory. Our findings contribute an effective technique for the fabrication of high-Q factor microlasers that may be potential for applications in biological and chemical sensors.

Robust Whispering-Gallery-Mode Microbubble Lasers from Colloidal Quantum Dots.

Microlasers hold great promise for the development of photonics and optoelectronics. Among the discovered optical gain materials, colloidal quantum dots (CQDs) have been recognized as the most appealing candidate due to the facile emission tunability and solution processability. However, to date, it is still challenging to develop CQD-based microlasers with low cost yet high performance. Moreover, the poor long-term stability of CQDs remains to be the most critical issue, which may block their laser aspirations. Herein, we developed a unique but generic approach to forming a novel type of a whispering-gallery-mode (WGM) microbubble laser from the hybrid CQD/poly(methyl methacrylate) (PMMA) nanocomposites. The formation mechanism of the microbubbles was unraveled by recording the drying process of the nanocomposite droplets. Interestingly, these microbubbles naturally serve as the high-quality WGM laser resonators. By simply changing the CQDs, the lasing emission can be tuned across the whole visible spectral range. Importantly, these microbubble lasers exhibit unprecedented long-term stability (over one year), sufficient for practical applications. As a proof-of-concept, the potential of water vapor sensing was demonstrated. Our results represent a significant advance in microlasers based on the advantageous CQDs and may offer new possibilities for photonics and optoelectronics.

Exciton localization and optical properties improvement in nanocrystal-embedded ZnO core-shell nanowires.

We present a comparative investigation of the morphological, structural, and optical properties of vertically aligned ZnO nanowires (NWs) before and after high energy argon ion (Ar(+)) milling. It is found that the outer regions of the as-grown sample change from crystalline to amorphous, and ZnO core-shell NWs with ZnO nanocrystals embedded are formed after Ar(+) milling. Optical properties of the ZnO NWs have been investigated systematically through power and temperature dependent photoluminescence measurements, and the phenomenon of exciton localization as well as the relevant favorable photoluminescence characteristics is elucidated. Interestingly, under high density optical pumping at room temperature, coherent random lasing action is observed, which is ascribed to exciton localization and strong scattering. Our results on the unique optical properties of localized exciton in ZnO core-shell nanostructures shed light on developing stable and high-efficiency excitonic optoelectronic devices such as light-emitting diodes and lasers.

Multicolor hybrid upconversion nanoparticles and their improved performance as luminescence temperature sensors due to energy transfer.

By combining upconversion nanoparticles (UCNPs) with rhodamine 6G (R6G) dye molecules, multicolor emission based on energy transfer is achieved. The complexes can be dissolved in epoxy resin, and self-assembled hemispherical microstructures are fabricated through a hydrophobic effect. A luminescence temperature sensor takes advantage of the high temperature sensitivity of the complexes due to energy transfer.

Dome-shaped mode lasing from liquid crystals for full-color lasers and high-sensitivity detection.

In this communication, we report a new class of oscillation mode, dome-shaped mode (DSM), in liquid crystal (LC) microlasers. A record high Q-factor over 24 000 is achieved in LC soft-matter microlasers. We successfully presented a proof-of-concept demonstration of red, green, blue (RGB) LC-DSM microlaser pixels with a 74% broader achievable color gamut than the standard RGB color space. Besides, the detection limit for acetone vapor molecules is as low as 0.5 ppm, confirming the excellent potential of the proposed LC-DSM microlaser in ultra-high sensitivity detection.

Ultralow-Threshold and High-Quality Whispering-Gallery-Mode Lasing from Colloidal Core/Hybrid-Shell Quantum Wells.

The realization of efficient on-chip microlasers with scalable fabrication, ultralow threshold, and stable single-frequency operation is always desired for a wide range of miniaturized photonic systems. Herein, an effective way to fabricate nanostructures- whispering-gallery-mode (WGM) lasers by drop-casting CdSe/CdS@Cd1- x Znx S core/buffer-shell@graded-shell nanoplatelets (NPLs) dispersion onto silica microspheres is presented. Benefiting from the excellent gain properties from the interface engineered core/hybrid shell NPLs and high-quality factor WGM resonator from excellent optical field confinement, the proposed room-temperature NPLs-WGM microlasers show a record-low lasing threshold of 3.26 µJ cm-2 under nanosecond laser pumping among all colloidal NPLs-based lasing demonstrations. The presence of sharp discrete transverse electric- and magnetic-mode spikes, the inversely proportional dependence of the free spectra range on microsphere sizes and the polarization anisotropy of laser output represent the first direct experimental evidence for NPLs-WGM lasing nature, which is verified theoretically by the computed electric-field distribution inside the microcavity. Remarkably, a stable single-mode lasing output with an ultralow lasing threshold of 3.84 µJ cm-2 is achieved by the Vernier effect through evanescent field coupling. The results highlight the significance of interface engineering on the optimization of gain properties of heterostructured nanomaterials and shed light on developing future miniaturized tunable coherent light sources.

Wide-range coupling between surface plasmon polariton and cylindrical dielectric waveguide mode.

A modified hybrid waveguide with a wide-range coupling and long propagation has been proposed and the coupled mode theory has been applied to study the hybrid waveguide systematically. Two structures are comparatively discussed, namely, a dielectric wire and a circular capillary tube, which are buried in a polymer matrix and separated from the silver substrate by a gap. The simulated results indicate that the circular capillary tube demonstrates a stronger coupling between the surface plasmon polariton and the waveguide mode compared to the solid dielectric wire. Furthermore, the electric field is highly confined in the gap area and can propagate several hundred micrometers.

Flexible and tensile microporous polymer fibers for wavelength-tunable random lasing.

Polymer micro-/nanofibers, due to their low-cost and mechanical flexibility, are attractive building blocks for developing lightweight and flexible optical circuits. They are also versatile photonic materials for making various optical resonators and lasers, such as microrings, networks and random lasers. In particular, for random lasing architectures, the demonstrations to-date have mainly relied on fiber bundles whose properties are hard to tune post-fabrication. Here, we demonstrate the successful implementation of an inverted photonic glass structure with monodisperse pores of 1.28 µm into polymer fibers with diameter ranging from 10 to 60 µm. By doping organic dye molecules into this structure, individual fibers can sustain random lasing under optical pulse excitation. The dependence of lasing characteristics, including lasing spectrum and lasing threshold on fiber diameter are investigated. It is found that the lasing emission red-shifts and the threshold decreases with increasing fiber diameter. Furthermore, owing to the mechanical flexibility, the lasing properties can be dynamically changed upon stretching, leading to a wavelength-tunability of 5.5 nm. Our work provides a novel architecture for random lasers which has the potential for lasing tunability and optical sensing.

Controllable Polarization of Lasing Emission From a Polymer Microfiber Laser.

Microlasers with controllable polarization of output emission are vital for on-chip optical communications, optical sensors and optical switches. In this work, we report a high quality (Q) factor, low-threshold polymer microfiber laser and the possibility of achieving laser emission with a desired polarization. The microfiber is fabricated by direct drawing from a dye-doped polymer solution and it can generate whispering gallery mode (WGM) lasing under optical pulse excitation. When the microfiber is pumped from the side with pumping direction perpendicular to the microfiber's axis, the polarization direction of the output laser is found to be the same as that of the pump laser. Lasing emission with either transverse electric (TE) or transverse magnetic (TM) modes can be obtained and these two polarization states can be switched over by tuning the pumping laser. Furthermore, emission with both TE and TM modes can also be observed by changing the orientation of the microfiber relatively to pumping direction. Our finding provides an effective approach for achieving microlasers that have high Q lasing modes with anticipated polarization.

Reconfigurable Liquid Whispering Gallery Mode Microlasers.

Engineering photonic devices from liquid has been emerging as a fascinating research avenue. Reconfigurably tuning liquid optical micro-devices are highly desirable but remain extremely challenging because of the fluidic nature. In this article we demonstrate an all-liquid tunable whispering gallery mode microlaser floating on a liquid surface fabricated by using inkjet print technique. We show that the cavity resonance of such liquid lasers could be reconfigurably manipulated by surface tension alteration originated from the tiny concentration change of the surfactant in the supporting liquid. As such, remarkable sensing of water-soluble organic compounds with a sensitivity of free spectral range as high as 19.85 THz / (mol · mL(-1)) and the detectivity limit around 5.56 × 10(-3) mol · mL(-1) is achieved. Our work provides not only a novel approach to effectively tuning a laser resonator but also new insight into potential applications in biological, chemical and environmental sensing.

Blue liquid lasers from solution of CdZnS/ZnS ternary alloy quantum dots with quasi-continuous pumping.

A blue (ca. 440 nm) liquid laser with an ultra-low threshold through which quasi-continuous wave pumping is accessible is achieved by engineering unconventional ternary CdZnS/ZnS alloyed-core/shell QDs. Such an achievement is enabled by exploiting the novel gain media with minimal defects, suppressed Auger recombination, and large gain cross-section in combination with high-quality-factor whispering gallery mode resonators.

Observation of polarized gain from aligned colloidal nanorods.

In recent years, colloidal semiconductor nanorods have attracted great interest for polarized spontaneous emission. However, their polarized gain has not been possible to achieve so far. In this work we show the highly polarized stimulated emission from the densely packed ensembles of core-seeded nanorods in a cylindrical cavity. Here CdSe/CdS dot-in-rods were coated and aligned on the inner wall of a capillary tube, providing optical feedback for the nanorod gain medium. Results show that the polarized gain originates intrinsically from the aligned nanorods and not from the cavity and that the optical anisotropy of the nanorod ensemble was amplified with the capillary tube, resulting in highly polarized whispering gallery mode lasing. The highly polarized emission and lasing, together with easy fabrication and flexible incorporation, make this microlaser a promising candidate for important color conversion and enrichment applications including liquid crystal display backlighting and laser lighting.

Stimulated emission and lasing from CdSe/CdS/ZnS core-multi-shell quantum dots by simultaneous three-photon absorption.

Three-photon pumped stimulated emission and coherent random lasing from colloidal CdSe/CdS/ZnS core-multishell quantum dots are achieved for the first time. These results can offer new possibilities in biology and photonics, as well as at their intersection of biophotonics.

Tuning whispering gallery mode lasing from self-assembled polymer droplets.

Optical microcavities are important for both fundamental studies of light-matter interaction and applications such as microlasers, optical switches and filters etc... Tunable microresonators, in which resonant modes can be manipulated, are especially fascinating. Here we demonstrate a unique approach to mechanically tuning microresonators formed by polymer droplets with varying sizes. The droplets are self-assembly inside an elastic medium. By incorporating different dye molecules into the droplets, optically pumped lasing with selective wavelengths in a range of about 100 nm are achieved. Lasing action is ascribed to whispering gallery modes, verified by rigorous characterizations. Single longitudinal mode lasing is obtained when the droplet diameter is reduced to about 14 µm. Tuning lasing modes are clearly demonstrated by mechanical deformation. Our finding provides an excellent platform for exploring flexible and tunable microlasers for plastic optoelectronic devices.

Self-assembled flexible microlasers.

Hemispherical microresonators with tunable sizes are obtained based on the hydrophobic effect on distributed Bragg reflectors. Under optical excitation, whispering gallery mode lasing is observed from the dye-doped microresonators at room temperature. The results indicate the potential application of the flexible microresonators in photonic integrated circuits.