In-situ polymerized solid/quasi-solid polymer electrolyte for lithium-metal batteries: recent progress and perspectives.

In pursuit of high energy density, lithium metal batteries (LMBs) are undoubtedly the best choice. However, leakage and inevitable dendrite growth in liquid electrolytes seriously hinder its practical application. Solid/quasi-solid state electrolytes have emerged as an answer to solve the above issues. Especially, polymer electrolytes with excellent interface compatibility, high flexibility, and ease of machining have become a research hotspot for LMBs. Nevertheless, the interface contact between polymer electrolyte and inorganic electrode materials and the low ionic conductivity restrict its development. On account of these, in situ polymerized polymer electrolyte is proposed. Polymer solid electrolytes produced through in situ polymerization promote robust interface contact between the electrolyte and electrode while simplifying the preparation steps. This review summarized the latest research progress in in situ polymerized solid electrolytes for LMBs. These electrolytes were divided into three parts according to their polymerization methods: thermally induced polymerization, chemical initiator polymerization, ionizing radiation polymerization, and so on. Furthermore, we concluded the major challenges and future trends of in situ polymerized solid electrolytes for LMBs. It's hoped that this review will provide meaningful guidance on designing high-performance polymer solid electrolytes for LMBs.

Genome and metabolome analysis of Bacillus sp. Hex-HIT36: A newly screened functional microorganism for the degradation of 1-hexadecene in industrial wastewater.

1-Hexadecene has been detected at a level of mg/L in both influent and effluent of wastewater treatment plants situated in chemical/pharmaceutical industrial parks, which poses a potential threat to the environment. However, few reports are available on aerobic metabolic pathways and microorganisms involved in 1-Hexadecene degradation. In this study, a new strain of 1-Hexadecene-degrading bacteria, Bacillus sp. Hex-HIT36 (HIT36), was isolated from the activated sludge of a wastewater treatment plants located in an industrial park. The physicochemical properties and degradation efficacy of HIT36 were investigated. HIT36 was cultured on a medium containing 1-Hexadecene as a sole carbon source; it was found to remove ∼67% of total organic carbon as confirmed by mass spectrometric analysis of intermediate metabolites. Metabolomic and genomic analysis showed that HIT36 possesses various enzymes, namely, pyruvate dehydrogenase, dihydropolyhydroxyl dehydrogenase, and 2-oxoglutarate-2-oxoiron oxidoreductase (subunit alpha), which assist in the metabolization of readily available carbon source or long chain hydrocarbons present in the growth medium/vicinity. This suggests that HIT36 has efficient long-chain alkane degradation efficacy, and understanding the alkane degradation mechanism of this strain can help in developing technologies for the degradation of long-chain alkanes present in wastewater, thereby assisting in the bioremediation of environment.

Enterobacter sp. HIT-SHJ4 isolated from wetland with carbon, nitrogen and sulfur co-metabolism and its implication for bioremediation.

Both autotrophic and heterotrophic denitrification are known as important bioprocesses of microbe-mediated nitrogen cycle in natural ecosystems. Actually, mixotrophic denitrification co-driven by organic matter and reduced sulfur substances are also common, especially in hypoxic environments such as estuarine sediments. However, carbon, nitrogen and sulfur co-metabolism during mixotrophic denitrification in natural water ecosystems has rarely been reported in detail. Therefore, this study investigated the co-metabolism of carbon, nitrogen and sulfur using samples collected from four distinct natural water ecosystems. Results demonstrated that samples from various sources all exhibited the ability for co-metabolism of carbon, nitrogen and sulfur. Microbial community analysis showed that Pseudomonas and Paracoccus were dominant bacteria ranging from 65.6% to 75.5% in mixotrophic environment. Enterobacter sp. HIT-SHJ4, a mixotrophic denitrifying strain which owned the capacity for co-metabolism of carbon, nitrogen and sulfur, was isolated and reported here for the first time. The strain preferred methanol as its carbon source and demonstrated remarkable efficiency for removing sulfide and nitrate with below 100 mg/L sulfide. Under weak acid conditions (pH 6.5-7.0), it exhibited enhanced capability in converting sulfide to elemental sulfur. Its bioactivity was evident within a temperature from 25 °C to 40 °C and C/N ratios from 0.75 to 3. This study confirmed the widespread presence of microbial-mediated synergistic carbon, nitrogen and sulfur metabolism in natural aquatic ecosystems. HIT-SHJ4 emerges as a novel strain, shedding light on carbon, nitrogen and sulfur co-metabolism in natural water bodies. Furthermore, it also serves as a promising candidate microorganism for in-situ ecological remediation, particularly in dealing with contamination posed by nitrate, sulfide, and organic matter.

Construction of the Fast Potassiation Path in Sbx Bi1-x @NC Anode with Ultrahigh Cycling Stability for Potassium-Ion Batteries.

Due to the scarce of lithium resources, potassium-ion batteries (PIBs) have attracted extensive attention due to their similar electrochemical properties to lithium-ion batteries (LIBs) and more abundant potassium resources. Even though there is considerable progress in SbBi alloy anode for LIBs and PIBs, most studies are focused on the morphology/structure tuning, while the inherent physical features of alloy composition's effect on the electrochemical performance are rarely investigated. Herein, combined the nanonization, carbon compounding, and alloying with composition regulation, the anode of nitrogen-doped carbon-coated Sbx Bi1-x (Sbx Bi1-x @NC) with a series of tuned chemical compositions is designed as an ideal model. The density functional theory (DFT) calculation and experimental investigation results show that the K+ diffusion barrier is lower and the path is easier to carry out when element Bi dominates the potassiation reaction, which is also the reason for better circulation. The optimized Sb0.25 Bi0.75 @NC shows an excellent cycling performance with a reversible specific capacity of 301.9 mA h g-1 after 500 cycles at 0.1 A g-1 . Meanwhile, the charge-discharge mechanism is intuitively invetigated and analyzed by in situ X-ray diffraction (XRD) and transmission electron microscopy (TEM) in detail. Such an alloy-type anode synthesis approach and in situ observation method provide an adjustable strategy for the designing and investigating of PIB anodes.

Defects-Abundant Ga2 O3 Nanobricks Enabled Multifunctional Solid Polymer Electrolyte for Superior Lithium-Metal Batteries.

Polyethylene oxide (PEO)-based polymer electrolytes with good flexibility and viscoelasticity, low interfacial resistance, and fabricating cost have caught worldwide attention, but their practical application is still hampered by the instability at high voltages and the low ionic conductivity (10-8 to 10-6  S cm-1 ). Herein, we rationally designed defects-abundant Ga2 O3 nanobricks as multifunctional fillers and constructed a PEO-based organic-inorganic electrolyte for lithium metal batteries. Due to the abundant O-defects feature of Ga2 O3 filler, this PEO-based composite electrolyte not only broadens electrochemical stability window (over 5.3 V versus Li/Li+ ) but also in situ forms a Li-Ga alloy and solid electrolyte interphase (SEI) film during the cycling process causing a rapid diffusion of Li+ ions. The as-prepared electrolyte has good interface compatibility with Li metal (without short-circuiting over 500 h at 0.2 mA cm-2 ) and possesses superior high ionic conductivity. The assembled all-solid-state LiFePO4 //Li cells attained an excellent cycling performance of 146 mAh g-1 over 100 cycles at 0.5 C. The XPS analysis reveals that Ga2 O3 nanobricks can form in situ a Li-Ga alloy layer at the polymer/anode interface. This work shed a light on designing high ionic conductivity lithium alloys in the composite electrolyte, which can improve the electrochemical properties of PEO-based polymer electrolytes.

Eutectic-Based Polymer Electrolyte with the Enhanced Lithium Salt Dissociation for High-Performance Lithium Metal Batteries.

The deployment of lithium metal anode in solid-state batteries with polymer electrolytes has been recognized as a promising approach to achieving high-energy-density technologies. However, the practical application of the polymer electrolytes is currently constrained by various challenges, including low ionic conductivity, inadequate electrochemical window, and poor interface stability. To address these issues, a novel eutectic-based polymer electrolyte consisting of succinonitrile (SN) and poly (ethylene glycol) methyl ether acrylate (PEGMEA) is developed. The research results demonstrate that the interactions between SN and PEGMEA promote the dissociation of the lithium difluoro(oxalato) borate (LiDFOB) salt and increase the concentration of free Li+ . The well-designed eutectic-based PAN1.2 -SPE (PEGMEA: SN=1: 1.2 mass ratio) exhibits high ionic conductivity of 1.30 mS cm-1 at 30 °C and superior interface stability with Li anode. The Li/Li symmetric cell based on PAN1.2 -SPE enables long-term plating/stripping at 0.3 and 0.5 mA cm-2 , and the Li/LiFePO4 cell achieves superior long-term cycling stability (capacity retention of 80.3 % after 1500 cycles). Moreover, Li/LiFePO4 and Li/LiNi0.6 Co0.2 Mn0.2 O2 pouch cells employing PAN1.2 -SPE demonstrate excellent cycling and safety characteristics. This study presents a new pathway for designing high-performance polymer electrolytes and promotes the practical application of high-stable lithium metal batteries.

In-Situ Synthesis of Carbon-Encapsulated Atomic Cobalt as Highly Efficient Polysulfide Electrocatalysts for Highly Stable Lithium-Sulfur Batteries.

Lithium-sulfur (Li-S) batteries have been considered as one of the most promising electrochemical energy storage systems because of their high energy density. However, a series of issues severely limit the practical performances of Li-S batteries such as low conductivity, significant volume change, and shuttle effect. The hollow carbon spheres with huge voids and high electrical conductivity are promising as sulfur hosts. Unfortunately, the nonpolar nature of carbon materials cannot prevent the shuttle effect effectively. In this case, the atomic cobalt is introduced to a nitrogen-doped hollow carbon sphere (ACo@HCS) through polymerization and controlled pyrolysis. The atomic cobalt dopants not only act as active sites to restrict the shuttle effect, but also can promote the kinetics of the sulfur redox reactions. ACo@HCS acting as sulfur host exhibits a high discharge capacity (1003 mAh g-1 ) at a 1.0 C rate after 500 cycles, and the corresponding decay rate is as low as 0.002% per cycle. This exciting work paves a new way to design high-performance Li-S batteries.

Cryptic Sulfur and Oxygen Cycling Potentially Reduces N2O-Driven Greenhouse Warming: Underlying Revision Need of the Nitrogen Cycle.

Increasing global deoxygenation has widely formed oxygen-limited biotopes, altering the metabolic pathways of numerous microbes and causing a large greenhouse effect of nitrous oxide (N2O). Although there are many sources of N2O, denitrification is the sole sink that removes N2O from the biosphere, and the low-level oxygen in waters has been classically thought to be the key factor regulating N2O emissions from incomplete denitrification. However, through microcosm incubations with sandy sediment, we demonstrate here for the first time that the stress from oxygenated environments does not suppress, but rather boosts the complete denitrification process when the sulfur cycle is actively ongoing. This study highlights the potential of reducing N2O-driven greenhouse warming and fills a gap in pre-cognitions on the nitrogen cycle, which may impact our current understanding of greenhouse gas sinks. Combining molecular techniques and kinetic verification, we reveal that dominant inhibitions in oxygen-limited environments can interestingly undergo triple detoxification by cryptic sulfur and oxygen cycling, which may extensively occur in nature but have been long neglected by researchers. Furthermore, reviewing the present data and observations from natural and artificial ecosystems leads to the necessary revision needs of the global nitrogen cycle.

Simultaneous removal of NOX and SO2 from flue gas in an integrated FGD-CABR system by sulfur cycling-mediated Fe(II)EDTA regeneration.

Chemical absorption-biological reduction (CABR) process is an attractive method for NOX removal and Fe(II)EDTA regeneration is important to sustain high NOX removal. In this study a sustainable and eco-friendly sulfur cycling-mediated Fe(II)EDTA regeneration method was incorporated in the integrated biological flue gas desulfurization (FGD)-CABR system. Here, we investigated the NOX and SO2 removal efficiency of the system under three different flue gas flows (100 mL/min, 500 mL/min, and 1000 mL/min) and evaluated the feasibility of chemical Fe(III)EDTA reduction by sulfide in series of batch tests. Our results showed that complete SO2 removal was achieved at all the tested scenarios with sulfide, thiosulfate and S0 accumulation in the solution. Meanwhile, the total removal efficiency of NOX achieved ∼100% in the system, of which 3.2%-23.3% was removed in spray scrubber and 76.7%-96.5% in EGSB reactor along with no N2O emission. The optimal pH and S2-/Fe(III)EDTA for Fe(II)EDTA regeneration and S0 recovery was 8.0 and 1:2. The microbial community analysis results showed that the cooperation of heterotrophic denitrifier (Saprospiraceae_uncultured and Dechloromonas) and iron-reducing bacteria (Klebsiella and Petrimonas) in EGSB reactor and sulfide-oxidizing, nitrate-reducing bacteria (Azoarcus and Pseudarcobacter) in spray scrubber contributed to the efficient removal of NOX in flue gas.

A novel intra- and extracellular distribution pattern of elemental sulfur in Pseudomonas sp. C27-driven denitrifying sulfide removal process.

Pseudomonas sp. C27 can achieve the conversion of toxic sulfide to economical elemental sulfur (S0) with various electron acceptors. In this study the distribution pattern of S0 produced by C27 in denitrifying sulfide removal (DSR) process was explored. The SEM observation identified that the particle size of the biogenic S0 was at micron level. Strikingly, a novel distribution pattern of S0 was revealed that the produced S0 was not directly secreted extracellularly, but be stored temporarily in the cell interior. Pyrolysis at 65 °C for 20 min were recommended prior to S0 recovery, which could maximize the separation of extracellular polymeric substances (EPS) from C27. Furthermore, the effects of N/S molar ratio, initial sulfide concentration, and micro-oxygen condition were investigated to improve the production of S0 by C27. The highest S0 production was obtained at S/N of 3 and anaerobic condition seemed to favor the S0 production by C27. This study would provide a theoretical support for highly efficient sulfide removal as well as S0 recovery in sulfide-laden wastewater treatment.

Multifunctional Metal Phosphides as Superior Host Materials for Advanced Lithium-Sulfur Batteries.

For the past few years, a new generation of energy storage systems with large theoretical specific capacity has been urgently needed because of the rapid development of society. Lithium-sulfur (Li-S) batteries are regarded as one of the most promising candidates for novel battery systems, since their resurgence at the end of the 20th century Li-S batteries have attracted ever more attention, attributed to their notably high theoretical energy density of 2600 W h kg-1 , which is almost five times larger than that of commercial lithium-ion batteries (LIBs). One of the determining factors in Li-S batteries is how to design/prepare the sulfur cathode. For the sulfur host, the major technical challenge is avoiding the shuttling effect that is caused by soluble polysulfides during the reaction. In past decades, though the sulfur cathode has developed greatly, there are still some enormous challenges to be conquered, such as low utilization of S, rapid decay of capacity, and poor cycle life. This article spotlights the recent progress and foremost findings in improving the performance of Li-S batteries by employing multifunctional metal phosphides as host materials. The current state of development of the sulfur electrode of Li-S batteries is summarized by emphasizing the relationship between the essential properties of metal phosphide-based hybrid nanomaterials, the chemical reaction with lithium polysulfides and the latter's influence on electrochemical performance. Finally, trends in the development and practical application of Li-S batteries are also pointed out.

Cathodes for Aqueous Zn-Ion Batteries: Materials, Mechanisms, and Kinetics.

As concerns about the safety of lithium-ions batteries (LIBs) increases, aqueous zinc-ion batteries (ZIBs) with a lower cost, higher safety, and higher co-efficiency have attracted more and more interest. However, finding suitable cathode materials is still an urgent problem in ZIBs. In recent years, a lot of significant works have been reported, including manganese-based cathodes, vanadium-based cathodes, Prussian blue analog-based materials, and sustainable quinone cathodes. In this review, some typical cathode materials are introduced. The detailed storage mechanisms and methods for improving the reaction kinetics of the zinc ions are summarized. Finally, the issues, challenges, and the research directions are provided.

B,N Codoped Graphitic Nanotubes Loaded with Co Nanoparticles as Superior Sulfur Host for Advanced Li-S Batteries.

Lithium-sulfur batteries (LSBs) are considered as one of the best candidates for novel rechargeable batteries due to their high energy densities and abundant required materials. However, the poor conductivity and large volume expansion of sulfur and the "shuttle effect" of lithium polysulfides (LPSs) have significantly hindered the development and successful commercialization of LSBs. Bean-like B,N codoped carbon nanotubes loaded with Co nanoparticles (Co@BNTs), which can act as advanced sulfur hosts for the novel LSB cathode, are fabricated. Uniform graphitic nanotubes improve the conductivity of the electrode and load more electroactive sulfur and buffer volume expansion during the electrochemical reaction. In addition, loaded Co nanoparticles and codoped B,N sites can significantly suppress the "shuttle effect" of LPSs with strong chemical interaction. It is established that the Co nanoparticles and codoped B,N can provide more active sites to catalyze the redox reaction of sulfur cathode. This stable Co@BNTs-S cathode displays an exceptional electrochemical performance (1160 mA h g-1 after 200 cycles at 0.1 C) and outstanding stable cycle performance (1008 mA h g-1 after 400 cycles at 1.0 C with an extremely low attenuation rate of 0.038% per cycle).

Recent Progress of P2-Type Layered Transition-Metal Oxide Cathodes for Sodium-Ion Batteries.

Sodium-ion batteries (SIBs) have attracted much attention due to their abundance, easy accessibility, and low cost. All of these advantages make them potential candidates for large-scale energy storage. The P2-type layered transition-metal oxides (Nax TMO2 ; TM=Mn, Co, Ni, Ti, Fe, V, Cr, and a mixture of multiple elements) exhibit good Na+ ion conductivity and structural stability, which make them an excellent choice for the cathode materials of SIBs. Herein, the structural evolution, anionic redox reaction, some challenges, and recent progress of Nax TMO2 cathodes for SIBs are reviewed and summarized. Moreover, a detailed understanding of the relationship of chemical components, structures, phase compositions, and electrochemical performance is presented. This Review aims to provide a reference for the development of P2-type layered transition-metal oxide cathode materials for SIBs.

Fe3 O4 @C Nanotubes Grown on Carbon Fabric as a Free-Standing Anode for High-Performance Li-Ion Batteries.

Recently, Li-ion batteries (LIBs) have attracted extensive attention owing to their wide applications in portable and flexible electronic devices. Such a huge market for LIBs has caused an ever-increasing demand for excellent mechanical flexibility, outstanding cycling life, and electrodes with superior rate capability. Herein, an anode of self-supported Fe3 O4 @C nanotubes grown on carbon fabric cloth (CFC) is designed rationally and fabricated through an in situ etching and deposition route combined with an annealing process. These carbon-coated nanotube structured Fe3 O4 arrays with large surface area and enough void space can not only moderate the volume variation during repeated Li+ insertion/extraction, but also facilitate Li+ /electrons transportation and electrolyte penetration. This novel structure endows the Fe3 O4 @C nanotube arrays stable cycle performance (a large reversible capacity of 900 mA h g-1 up to 100 cycles at 0.5 A g-1 ) and outstanding rate capability (reversible capacities of 1030, 985, 908, and 755 mA h g-1 at 0.15, 0.3, 0.75, and 1.5 A g-1 , respectively). Fe3 O4 @C nanotube arrays still achieve a capacity of 665 mA h g-1 after 50 cycles at 0.1 A g-1 in Fe3 O4 @C//LiCoO2 full cells.

Recent Progress in Organic-Inorganic Composite Solid Electrolytes for All-Solid-State Lithium Batteries.

Conventional lithium-ion batteries, with flammable organic liquid electrolytes, have serious safety problems, which greatly limit their application. All-solid-state batteries (ASSBs) have received extensive attention from large-scale energy-storage fields, such as electric vehicles (EVs) and intelligent power grids, due to their benefits in safety, energy density, and thermostability. As the key component of ASSBs, solid electrolytes determine the properties of ASSBs. In past decades, various kinds of solid electrolytes, such as polymers and inorganic electrolytes, have been explored. Among these candidates, organic-inorganic composite solid electrolytes (CSEs) that integrate the advantages of these two different electrolytes have been regarded as promising electrolytes for high-performance ASSBs, and extensive studies have been carried out. Herein, recent progress in organic-inorganic CSEs is summarized in terms of the inorganic component, electrochemical performance, effects of the inorganic ceramic nanostructure, and ionic conducting mechanism. Finally, the main challenges and perspectives of organic-inorganic CSEs are highlighted for future development.

Dramatically Enhanced Li-Ion Storage of ZnO@C Anodes through TiO2 Homogeneous Hybridization.

Amorphous nanoparticles of ZnO and TiO2 embedded in carbon nanocages (AZT⊂CNCs) were successfully synthesized through a simple annealing process of TiO2 -coated zeolitic imidazolate framework-8 (ZIF-8). In the current anode of AZT⊂CNCs, tiny ZnO and TiO2 nanoparticles were uniformly distributed in the carbon matrix (carbon nanocages), which could effectively buffer the volume expansion of electroactive ZnO and provide excellent electric conductivity. After fully investigating the electrochemical performance of the AZT⊂CNCs samples obtained with different additive amounts of tetrabutyl orthotitanate (TBOT) for TiO2 coating, it has been found that AZT-30 (0.1 g ZIF-8 with 30 mL TBOT) shows the best cycle stability (510 mA h g-1 after 350 cycles at 200 mA g-1 ) and a superior rate capability (610 mA h g-1 after 3500 cycles at 2 A g-1 ). The greatly enhanced Li-ion storage performance could be ascribed to the fact that the introduction of amorphous TiO2 could activate the reversible lithiation/delithiation reaction of ZnO during the charge/discharge process.

Facile Synthesis of Peapod-Like Cu3 Ge/Ge@C as a High-Capacity and Long-Life Anode for Li-Ion Batteries.

As anode materials for high-performance Li-ion batteries, peapod-like Ge-based composites, including Ge, a Li-inactive conducting Cu3 Ge, and a porous carbon matrix are synthesized simply by annealing CuGeO3 @dopamine in a H2 /Ar atmosphere. The introduction of the carbon layer and inactive alloying phase Cu3 Ge not only enhances the electrical conductivity of the Ge anode, but also reduces the volume change of Ge during the cell cycle as a buffer. In particular, the anode of this peapod-like Cu3 Ge/Ge@C shows an excellent long cycle life as well as outstanding capacity performance, with a discharge specific capacity up to 934 mA h g-1 after 500 cycles.

FeP@C Nanotube Arrays Grown on Carbon Fabric as a Low Potential and Freestanding Anode for High-Performance Li-Ion Batteries.

An anode of self-supported FeP@C nanotube arrays on carbon fabric (CF) is successfully fabricated via a facile template-based deposition and phosphorization route: first, well-aligned FeOOH nanotube arrays are simply obtained via a solution deposition and in situ etching route with hydrothermally crystallized (Co,Ni)(CO3 )0.5 OH nanowire arrays as the template; subsequently, these uniform FeOOH nanotube arrays are transformed into robust carbon-coated Fe3 O4 (Fe3 O4 @C) nanotube arrays via glucose adsorption and annealing treatments; and finally FeP@C nanotube arrays on CF are achieved through the facile phosphorization of the oxide-based arrays. As an anode for lithium-ion batteries (LIBs), these FeP@C nanotube arrays exhibit superior rate capability (reversible capacities of 945, 871, 815, 762, 717, and 657 mA h g-1 at 0.1, 0.2, 0.4, 0.8, 1.3, and 2.2 A g-1 , respectively, corresponding to area specific capacities of 1.73, 1.59, 1.49, 1.39, 1.31, 1.20 mA h cm-2 at 0.18, 0.37, 0.732, 1.46, 2.38, and 4.03 mA cm-2 , respectively) and a stable long-cycling performance (a high specific capacity of 718 mA h g-1 after 670 cycles at 0.5 A g-1 , corresponding to an area capacity of 1.31 mA h cm-2 at 0.92 mA cm-2 ).

Self-Supported CoP Nanorod Arrays Grafted on Stainless Steel as an Advanced Integrated Anode for Stable and Long-Life Lithium-Ion Batteries.

To alleviate the capacity degradation of anode materials for Li-ion batteries, caused by serious volume expansion and particle aggregation, intensive attention has been devoted to the rational design and fabrication of novel anode architectures. Herein, self-supported CoP nanorod arrays have been facilely synthesized using hydrothemally deposited Co(CO3 )0.5 (OH)⋅0.11 H2 O nanorod arrays as the precursor, through a gas-phase phosphidation method. As the anode for Li-ion batteries, such 3D interconnected CoP nanorod arrays show an initial discharge capacity of 1067 mAh g-1 and a high reversible charge capacity of 737 mAh g-1 at 0.4 Ag-1 . After 400 cycles, their specific capacity can reach 510 mAh g-1 ; even after 900 cycles, they can still deliver a specific capacity of 390 mAh g-1 . CoP//LiCoO2 full-cells also exhibit a high reversible capacity of 400 mAh g-1 after 50 cycles. These unique 3D interconnected CoP nanorod arrays also show ultrastable cycling performance over 500 cycles when used as the anode in a Na-ion battery.