Visible-Light-Responsive Photoreversible Multi-Color Switching for Rewritable Light-Printing and Information Display.

Photoreversible color switching systems (PCSSs) exhibiting multi-color responses to visible light are favored for sustainable societal development over those relying on ultraviolet light due to safer operation and better penetration depth. Here, a PCSS capable of multi-color switching responsive to visible light based on highly photoreductive rutile-phase Sn-doped TiO2-x nanoparticles is reported. The Sn-doping significantly red-shifts the absorption band of the nanoparticles to the visible region, improving charge separation and transfer efficiencies and introducing Ti3+ species and oxygen vacancies as internal sacrificial electron donors for scavenging photogenerated holes. The resulting Sn-doped TiO2-x nanoparticles feature exceptional photoreduction ability and activity, thereby enabling photoreversible color switching of various redox dyes operational under visible light illumination. Furthermore, multi-color switching can be achieved via the color overlay effect by combining different redox dyes in one system, opening the door to many advanced applications, as demonstrated in their successful uses for developing visible-light-driven rewritable multi-color light-printing systems and visual information displays.

Self-Powered Flexible Multicolor Electrochromic Devices for Information Displays.

The development of self-powered flexible multicolor electrochromic (EC) systems that could switch different color without an external power supply has remained extremely challenging. Here, a new trilayer film structure for achieving self-powered flexible multicolor EC displays based on self-charging/discharging mechanism is proposed, which is simply assembled by sandwiching an ionic gel film between 2 cathodic nickel hexacyanoferrate (NiHCF) and Prussian blue (PB) nanoparticle films on indium tin oxide substrates. The display exhibits independent self-powered color switching of NiHCF and PB films with fast responsive time and high reversibility by selectively connecting the Al wire as anodes with the 2 EC films. Multicolor switching is thus achieved through a color overlay effect by superimposing the 2 EC films, including green, blue, yellow, and colorless. The bleaching/coloration process of the displays is driven by the discharging/self-charging mechanism for NiHCF and PB films, respectively, ensuring the self-powered color switching of the displays reversibly without an external power supply. It is further demonstrated that patterns can be easily created in the self-powered EC displays by the spray-coating method, allowing multicolor changing to convey specific information. Moreover, a self-powered ionic writing board is demonstrated based on the self-powered EC displays that can be repeatedly written freehand without the need of an external power source. We believe that the design concept may provide new insights into the development of self-powered flexible multicolor EC displays with self-recovered energy for widespread applications.

An AIRE-active far-red ratiometric fluorescent chemosensor for specifically sensing Zn2+ and resultant Zn2+ complex for subsequent pyrophosphate detection in almost pure aqueous media.

A simple Schiff-base fluorescent chemosensor (1) was synthesized by the reaction of 3-amino-pyrazine-2-carbohydrazide and 7-diethylamino-3-formylcoumarin; the sensor 1 displayed a notable green emission at 524 nm in DMSO and an aggregation-induced ratiometric emission (AIRE) at 555 nm in an almost buffered aqueous media (0.5% DMSO content). The AIRE of 1 was quenched following binding to Zn2+ ions, while the fluorescence emission in the far-red region was evidently enhanced at 628 nm. Notably, the ratiometric signal output could be utilized to specifically distinguish Zn2+ among various metal ions. Moreover, the 1-Zn2+ complex was effectively employed as a fluorescent ratiometric chemosensor for pyrophosphate (PPi) detection. The detection limit was 3.52 µM and 2.45 µM for Zn2+ and PPi, respectively. The binding mechanism was evaluated by 1H NMR, ESI-MS, single-crystal X-ray diffraction, TEM, time-resolved fluorescence spectrophotometry, and density functional theory studies. Overall, owing to its sensitive fluorescence behavior, cell imaging studies demonstrated that this sensor is capable of sensing Zn2+ and PPi in living cells.