Ultra-Durable Polysilicon Based Tribovoltaic Nanogenerators for Bearing In Situ Rotational Speed Sensing.

Tribovoltaic nanogenerator (TVNG) is an emerging energy device with the advantages of direct current and high power density. At present, many TVNGs are based on single-crystal materials, which are expensive and fragile during structural processing. Here, a polysilicon-based TVNG for bearing in situ rotational speed sensing is developed, which has the same level of performance and lower cost compared to monocrystalline silicon. The defects in polysilicon can provide additional carriers, but the grain boundaries can suppress the transport process of carriers, resulting in almost the same electrical output as single crystals. The oiled sliding mode TVNG has an impressive durability of up to 1 million cycles. The friction coefficient of rolling mode TVNG is as low as 0.14. Based on rolling mode polysilicon TVNG, the tapered roller bearing, thrust ball bearing, and deep groove ball bearing are manufactured by cutting and engraving processes. Moreover, their short-circuit current and open-circuit voltage are linear with speed, and the fitting coefficient is as high as 0.99, providing favorable conditions for in situ rotational speed sensing. This work presents a structure-function integrated bearing design methodology, demonstrating the considerable potential of in situ sensing for intelligent components in the industrial Internet of Things.

Compact and efficient high-power mid-infrared supercontinuum fiber laser source based on a noise-like pulse and germania fiber.

Here, we demonstrate a compact and efficient high-power mid-infrared supercontinuum (MIR-SC) laser source based on a tunable noise-like pulse (NLP) fiber laser system and a short section of single-mode germania-core fiber (GCF). The NLP all-polarization-maintaining fiber laser system can deliver the maximum output power of ∼30.6 W and a broadband spectrum (∼1.8-2.7 µm) with a compact single-stage fiber amplifier. By directly pumping only ∼6.5 cm-long GCF with a core diameter of ∼3.5 µm, a MIR-SC (spectral coverage of ∼1.5-3.3 µm) with a maximum power of ∼25.2 W and a power conversion efficiency ∼81.2% is obtained, which represent the highest power and efficiency in any single-mode GCF-based MIR-SCs, to the best of our knowledge. Our study contributes to the high-power MIR-SC laser source with compact all-fiber configuration, and will prompt its practical applications.

5.4 W, 2.35†µm cascaded Raman fiber laser pumped by dissipative soliton resonance-like pulses.

We present a nonlinear amplifying loop mirror-based mode-locked fiber laser. By adjusting the pump power, the proposed laser exhibits a dissipative soliton resonance (DSR)-like pulse operation with a maximum pulse width of 150 ns. Subsequently, a three-stage Tm3+-doped fiber amplifier is implemented using a single-mode double-cladding Tm3+-doped fiber to increase the DSR-like pulse output power to 52.5 W, achieving a pump slope efficiency of 47.1% in the main amplifier. A 25 m first-order Raman-gain fiber (UHNA7) is pumped by a DSR-like pulse, and 16.3 W of pure 2.135 µm first-order Raman light with a spectral purity of 73.4% is obtained. Finally, 5.4 W of 2.35 µm second-order Raman light with a spectral purity of 66% is obtained using a 10 m 98% germania-core fiber as a second-order Raman-gain fiber cascaded after UHNA7 fiber. To the best of our knowledge, this is the highest output power ever obtained from a 2.3 µm laser.

Over 3.8 W, 3.4†µm picosecond mid-infrared parametric conversion based on a simplified one-to-many scheme.

In this paper, we demonstrate a simplified one-to-many scheme for efficient mid-infrared (MIR) parametric conversion. Such a scheme is based on a continuous wave (CW) single longitudinal mode master oscillator power-amplifier (MOPA) fiber system as the signal source and a picosecond pulsed MOPA fiber system, exhibiting multiple longitudinal modes, as the pump source. The signal and pump beams are combined and co-coupled into a piece of 50-mm long 5% MgO-doped PPLN crystal for the parametric conversion. As high as ∼3.82 W average power at a central idler wavelength of ∼3.4 µm is achieved when the launched pump and signal powers are ∼41.73 and ∼11.45 W, respectively. Above some threshold value, the delivered idler power shows a roll-over effect against the signal power and saturation-like effect against the pump power. Consequently, the highest conversion efficiency is observed at such a threshold pump power. To the best of our knowledge, our result represents the highest average power produced from any single-pass parametric conversion source with >3 µm idler wavelength feeding with a CW signal. Moreover, our proposed scheme can simplify the design of parametric conversion system significantly and meanwhile make the system more robust in applications. This is attributed to two main aspects. Firstly, the scheme's one-to-many feature can reduce wavelength sensitivity remarkably in the realization of quasi-phase-matching. Secondly, for moderate power requirement it does not always require a high peak power synchronized pulsed signal source; a CW one can be an alternative, thereby making the system free from complex time synchronization and the related time jitter.

Cavity-birefringence-based manipulation of long-duration optical pulses in a passively mode-locked fiber laser with large normal dispersion.

Optical pulse manipulation in the large normal dispersion regime through intracavity birefringence management is demonstrated experimentally in an erbium-doped fiber (EDF) laser, for the first time to the best of our knowledge. The EDF laser is passively mode-locked based on a nonlinear amplifying loop mirror (NALM) in a figure-of-eight (f-8) configuration. Different lengths of the same type of polarization-maintaining fiber (PMF) are incorporated into the NALM to vary the net cavity birefringence. For each length of PMF, various polarization states and pump powers were tested and compared to achieve a pulse duration tuning range as large as possible. For comparison, these polarization states and pump powers were also studied by incorporating the PMF into the unidirectional loop of the f-8 cavity. Our results reveal some new features for the management of cavity birefringence that can enable long-duration pulse manipulation in the large normal dispersion regime.

Multi-scale simulation of proton diffusion in dislocation cores in BaZrO3.

Dislocations are important for their effects on the chemical, electrical, magnetic, and transport properties of oxide materials, especially for electrochemical devices such as solid fuel cells and resistive memories, but these effects are still under-studied at the atomic level. We have developed a quantum mechanical/molecular mechanical (QM/MM)-based multiscale simulation program to reveal the diffusion properties of protons on 〈100〉 edge dislocations in BaZrO3 perovskite oxide. We find that the large free space and the presence of hydrogen bonds in the dislocation core structure lead to significant trapping of protons. The diffusion properties of protons in dislocation cores were investigated, and no evidence of pipeline diffusion was found from the calculated migration energy barriers, which not only did not accelerate ion diffusion but rather decreases the conductivity of ions. The proton diffusion properties of Y-doped BaZrO3 (BZY), with a dislocation core structure (BZY-D) and with a grain boundary structure (BZY-GB) were also compared. In all three structures, local lattice deformation occupies an essential part in the proton transfer and rotation processes. The change in bond order is calculated and it is found that the interaction with oxygen and Zr ions during proton transfer and rotation controls the energy barrier for local lattice deformation of the O-B-O motion, which affects the proton diffusion in the structure. Our study provides insight into proton diffusion in dislocations in terms of mechanical behavior, elucidates the origin of the energy barrier associated with proton diffusion in dislocations, and provides guidance for the preparation and application of proton conductors.

Triboelectric Nanogenerators as Active Tactile Stimulators for Multifunctional Sensing and Artificial Synapses.

The wearable tactile sensors have attracted great attention in the fields of intelligent robots, healthcare monitors and human-machine interactions. To create active tactile sensors that can directly generate electrical signals in response to stimuli from the surrounding environment is of great significance. Triboelectric nanogenerators (TENGs) have the advantages of high sensitivity, fast response speed and low cost that can convert any type of mechanical motion in the surrounding environment into electrical signals, which provides an effective strategy to design the self-powered active tactile sensors. Here, an overview of the development in TENGs as tactile stimulators for multifunctional sensing and artificial synapses is systematically introduced. Firstly, the applications of TENGs as tactile stimulators in pressure, temperature, proximity sensing, and object recognition are introduced in detail. Then, the research progress of TENGs as tactile stimulators for artificial synapses is emphatically introduced, which is mainly reflected in the electrolyte-gate synaptic transistors, optoelectronic synaptic transistors, floating-gate synaptic transistors, reduced graphene oxides-based artificial synapse, and integrated circuit-based artificial synapse and nervous systems. Finally, the challenges of TENGs as tactile stimulators for multifunctional sensing and artificial synapses in practical applications are summarized, and the future development prospects are expected.

Self-Powered and Autonomous Vibrational Wake-Up System Based on Triboelectric Nanogenerators and MEMS Switch.

With the extensive application of wireless sensing nodes, the demand for sustainable energy in unattended environments is increasing. Here, we report a self-powered and autonomous vibrational wake-up system (SAVWS) based on triboelectric nanogenerators and micro-electromechanical system (MEMS) switches. The energy triboelectric nanogenerator (E-TENG) harvests vibration energy to power the wireless transmitter through a MEMS switch. The signal triboelectric nanogenerator (S-TENG) controls the state of the MEMS switch as a self-powered accelerometer and shows good linearity in the acceleration range of 1-4.5 m/s2 at 30 Hz with a sensitivity of about 14.6 V/(m/s2). When the acceleration increases, the S-TENG turns on the MEMS switch, and the wireless transmitter transmits an alarm signal with the energy from E-TENG, using only 0.64 mJ. Using TENGs simultaneously as an energy source and a sensor, the SAVWS provides a self-powered vibration monitoring solution for unattended environments and shows extensive applications and great promise in smart factories, autonomous driving, and the Internet of Things.

10 µJ noise-like pulse generated from all fiberized Tm-doped fiber oscillator and amplifier.

Herein, we presented a high energy noise-like (NL) pulse Tm-doped fiber laser (TDFL) system. Relying on the nonlinear amplifying loop mirror (NALM), stable noise-like pulses with coherence spike width of ∼317 fs and envelope width of ∼4.2 ns were obtained from an all polarization-maintaining fiberized oscillator at central wavelength of ∼1946.4 nm with 3 dB bandwidth of ∼24.9 nm. After the amplification in an all-fiberized TDF amplifier system, the maximum average output power of ∼32.8 W and pulse energy of ∼10.1 µJ were obtained, which represents the highest pulse energy of NL pulse at ∼2 µm, to the best of our knowledge. We believe that the high energy NL pulse source has the potential application in mid-infrared supercontinuum generation.

Over 10 W linearly polarized supercontinuum directly produced in an erbium-doped fiber MOPA seeded with stretched soliton.

We experimentally achieve over 10 W linearly polarized supercontinuum (SC) generation in a polarization-maintaining (PM) erbium-doped fiber (EDF) master oscillator power-amplifier (MOPA). The house-built PM seeding EDF laser can deliver ∼209fs soliton around ∼1563.7nm, which is then stretched to >15ps using a long piece of normal-dispersion fiber. The wideband spectrum of the ultrashort seeding soliton facilitates the further spectral broadening with nonlinear effects. The soliton stretching decelerates the peak power increase, thus facilitating higher amplified average power. After several stages of pre-amplification, the stretched soliton is fed into the main amplifier constructed with PM large mode area fibers. The output average power is finally amplified to ∼11.51W. The corresponding spectrum spans from ∼1450 to ∼2200nm, indicating that SC is formed due to the induced strong nonlinear effects. The polarization extinction ratio at the output reaches over 18 dB. The PM characteristic potentially enhances the system's resistance to environmental disturbances and eliminates instabilities relating to polarization-mode coupling. Our result represents, so far, the highest SC power directly produced in an EDF MOPA, to the best of our knowledge, especially in a linearly polarized manner. This also suggests a scheme for powerful SC generation that employs direct laser diode pumping and duration-managed pulse seeding.

Quantitative trait loci analysis of seed oil content and composition of wild and cultivated soybean.

BACKGROUND: Soybean oil is a major source of edible oil, and the domestication of wild soybean has resulted in significant changes in oil content and composition. Extensive efforts have been made to identify genetic loci that are related to soybean oil traits. The objective of this study was to identify quantitative trait loci (QTLs) related to soybean seed oil and compare the fatty acid composition between wild and cultivated soybean. RESULTS: Using the specific-locus amplified fragment sequencing (SLAF-seq) method, a total of 181 recombinant inbred lines (RILs) derived from a cross between wild soybean ZYD00463 (Glycine soja) and cultivated soybean WDD01514 (Glycine max) were genotyped. Finally, a high-density genetic linkage map comprising 11,398 single-nucleotide polymorphism (SNP) markers on 20 linkage groups (LGs) was constructed. Twenty-four stable QTLs for seed oil content and composition were identified by model-based composite interval mapping (CIM) across multiple environments. Among these QTLs, 23 overlapped with or were adjacent to previously reported QTLs. One QTL, qPA10_1 (5.94-9.98 Mb) on Chr. Ten is a novel locus for palmitic acid. In the intervals of stable QTLs, some interesting genes involved in lipid metabolism were detected. CONCLUSIONS: We developed 181 RILs from a cross between wild soybean ZYD00463 and cultivated soybean WDD01514 and constructed a high-density genetic map using the SLAF-seq method. We identified 24 stable QTLs for seed oil content and compositions, which includes qPA10_1 on Chr. 10, a novel locus for palmitic acid. Some interesting genes in the QTL regions were also detected. Our study will provide useful information for scientists to learn about genetic variations in lipid metabolism between wild and cultivated soybean.

Narrow-bandwidth h-shaped pulse generation and evolution in a net normal dispersion thulium-doped fiber laser.

We report on experimental generation and evolution of circumstance-susceptible, narrow-bandwidth, h-shaped pulse in a thulium-doped fiber (TDF) laser. With typical mode-locking technique based on nonlinear amplifying loop mirror, a type of h-shaped pulse is generated in a net normal dispersion regime for the first time to our best knowledge. Different from pulses with similar profiles achieved in typical anomalous dispersion regime, the h-shaped pulse here exhibits extremely narrow spectral bandwidth and meanwhile becomes highly circumstance-susceptible. Not alike the well-preserved h-shaped profile with anomalous dispersion, here the h-shaped pulse can easily evolve into various other pulse patterns with circumstance variations, including peak-depressed profiles, burst-like emission, multiple h-shaped pulses, and even some highly complex temporal cases. Despite that, the h-shaped pulse broadens as the pump power increasing, being a typical pump-related characteristic dominated by the peak-power-clamping effect. Moreover, it is observed that the h-shaped pulse profile can be re-shaped by incorporating a piece of unpumped TDF into the cavity, i.e., introducing some reabsorption. Our results substantiate the experimental revelation of such a type of particular-profile pulse in the normal dispersion regime, demonstrating some new evolution features facilitated by the dispersion-relevant circumstance-susceptibility.

Dissipative soliton resonance and its depression into burst-like emission in a holmium-doped fiber laser with large normal dispersion.

We report on dissipative soliton resonance (DSR) and its transformation into a type of burst-like emission in a holmium-doped fiber (HDF) laser in the large normal dispersion regime. A nonlinear amplifying loop mirror incorporating ∼118 m large normal dispersion fiber acts as an artificial saturable absorber. To the best of our knowledge, the HDF laser has the largest net normal dispersion so far. As the pump power is increased from ∼1.72 W to ∼4.80 W, the produced single pulse linearly broadens from ∼6.7 ns to ∼68.0 ns, while the output pulse peak power is clamped around ∼180.5 mW due to the peak-power-clamping effect with DSR. The sharp spectral peak indicates that DSR is realized with a large normal dispersion. With further manipulation of the polarization state, DSR can evolve into a type of burst-like emission. It is further revealed that this burst-like emission could be caused by a type of peak-power-depressing effect, which results from the competition between DSR and soliton formation.

Cavity-birefringence-dependent h-shaped pulse generation in a thulium-holmium-doped fiber laser.

We report on a type of 2 µm h-shaped pulse generation in a thulium-holmium-doped fiber laser and experimentally investigate its cavity birefringence and pump power dependences. An asymmetric nonlinear optical loop mirror is employed as an artificial saturable absorber, which incorporates ∼52.7 m dispersion-shifted fiber and ∼3.8 m ultra-high numerical aperture fiber to enhance the nonlinearity. The h-shaped pulse shows both a polarization state (PS) and pump power related evolutions, even when randomly weak birefringence fibers are employed. By further incorporating different lengths of high birefringence polarization-maintaining fiber (PMF), i.e., introducing different amounts of linear cavity birefringence, much larger pulse tuning ranges can be realized. In particular, when the PMF is lengthened to ∼2.3 m through manipulating the PS, the achieved longest pulse duration of ∼318.14 ns can almost cover the whole repetition period of ∼323.96 ns, corresponding to a pulse duty circle of ∼98.2%, the largest ever reported from a fiber laser, to the best of our knowledge. We demonstrate the related characteristics in detail.

100 W dissipative soliton resonances from a thulium-doped double-clad all-fiber-format MOPA system.

In this paper, we first achieve nanosecond-scale dissipative soliton resonance (DSR) generation in a thulium-doped double-clad fiber (TDF) laser with all-anomalous-dispersion regime, and also first scale the average power up to 100.4 W by employing only two stage TDF amplifiers, corresponding to gains of 19.3 and 14.4 dB, respectively. It is noted that both the fiber laser oscillator and the amplification system employ double-clad fiber as the gain medium for utilizing the advantages in high-gain-availability, high-power-handling and good-mode-quality-maintaining. DSR mode-locking of the TDF oscillator is realized by using a nonlinear optical loop mirror (NOLM), which exhibits all-fiber-format, high nonlinear and passive saturable absorption properties. The TDF oscillator can deliver rectangular-shape pulses with duration ranging from ~3.74 to ~72.19 ns while maintaining a nearly equal output peak power level of ~0.56 W, namely peak power clamping (PPC) effect. Comparatively, the two stage amplifiers can scale the seeding pulses to similar average power levels, but to dramatically different peak powers ranging from ~0.94 to ~18.1 kW depending on the durations. Our TDF master-oscillator-power-amplifier (MOPA) system can provide a high power 2-µm band all-fiber-format laser source both tunable in pulse duration and peak power.

Simultaneous electrochemical detection of multiple biomarkers using gold nanoparticles decorated multiwall carbon nanotubes as signal enhancers.

In this work, a novel sandwich-type electrochemical immunosensor has been developed for simultaneous detection of carcinoembryonic antigen (CEA) and α-fetoprotein (AFP) based on metal ion labels. Gold nanoparticles decorated multiwall carbon nanotubes (AuNPs@MWCNTs) were used as carriers to immobilize secondary antibodies and distinguishable electrochemical tags of Pb(2+) and Cd(2+) to amplify the signals. Due to the intrinsic property of high surface-to-volume ratio, the AuNPs@MWCNTs could load numerous secondary antibodies and labels. Therefore, the multiplexed immunoassay exhibited good sensitivity and selectivity. Experimental results revealed that this sandwich-type immunoassay displayed an excellent linear response, with a linear range of 0.01 to 60 ng mL(-1) for both analytes and detection limits of 3.0 pg mL(-1) for CEA and 4.5 pg mL(-1) for AFP (at a signal-to-noise ratio of 3). The method was successfully applied for the determination of AFP and CEA levels in clinical serum samples.

Horseradish peroxidase functionalized gold nanorods as a label for sensitive electrochemical detection of alpha-fetoprotein antigen.

In this study, a novel tracer, horseradish peroxidase (HRP) functionalized gold nanorods (Au NRs) nanocomposites (HRP-Au NRs), was designed to label the signal antibodies for sensitive electrochemical measurement of alpha-fetoprotein (AFP). The preparation of HRP-Au NRs nanocomposites and the labeling of secondary antibody (Ab2) were performed by one-pot assembly of HRP and Ab2 on the surface of Au NRs. The immunosensor was fabricated by assembling carbon nanotubes (CNTs), Au NRs, and capture antibodies (Ab1) on the glassy carbon electrode. In the presence of AFP antigen, the labels were captured on the surface of the Au NRs/CNTs via specific recognition of antigen-antibody, resulting in the signal intensity being clearly increased. Differential pulse voltammetry (DPV) was employed to record the response signal of the immunosensor in phosphate-buffered saline (PBS) containing hydrogen peroxide (H2O2) and 3,3',5,5'-tetramethylbenzidine (TMB). Under optimal conditions, the signal intensity was linearly related to the concentration of AFP in the range of 0.1-100 ng ml(-1), and the limit of detection was 30 pg ml(-1) (at signal/noise [S/N] = 3). Furthermore, the immunoassay method was evaluated using human serum samples, and the recovery obtained was within 99.0 and 102.7%, indicating that the immunosensor has potential clinical applications.

Tunable and switchable multi-wavelength dissipative soliton generation in a graphene oxide mode-locked Yb-doped fiber laser.

We report the generation of tunable single-, switchable and tunable dual-, and stable triple-wavelength dissipative solitons (DSs) in an all-normal-dispersion mode-locked Yb-doped fiber laser based on a graphene-oxide saturable absorber (GOSA) without additional components (such as optical filter, or fiber grating). The tunable single-wavelength DS have a wide wavelength-tunable range of 16.4 nm. The dual-wavelength DSs not only have a wavelength-tunable range (about 10 nm) but also have variable wavelength spacing (3.8-13.8 nm). The formation dynamics of the triple-wavelength DSs was also investigated experimentally. The different operations of tunable single-, switchable and tunable dual-, and stable triple-wavelength DSs depend on the strength of the cavity birefringence. The simple, compact all-fiber DS laser with lasing wavelength tunability and flexibility can meet great potential for applications.

A Degradable Tribotronic Transistor for Self-Destructing Intelligent Package e-Labels.

Recently, discarded electronic products have caused serious environmental pollution and information security issues, which have attracted widespread attention. Here, a degradable tribotronic transistor (DTT) for self-destructing intelligent package e-labels has been developed, integrated by a triboelectric nanogenerator and a protonic field-effect transistor with sodium alginate as a dielectric layer. The triboelectric potential generated by external contact electrification is used as the gate voltage of the organic field-effect transistor, which regulates carrier transport through proton migration/accumulation. The DTT has successfully demonstrated its output characteristics with a high sensitivity of 0.336 mm-1 and a resolution of over 100 µm. Moreover, the DTT can be dissolved in water within 3 min and completely degraded in soil within 12 days, demonstrating its excellent degradation characteristics, which may contribute to environmental protection. Finally, an intelligent package e-label based on the modulation of the DTT is demonstrated, which can display information about the package by a human touch. The e-label will automatically fail due to the degradation of the DTT over time, achieving the purpose of information confidentiality. This work has not only presented a degradable tribotronic transistor for package e-labels but also exhibited bright prospects in military security, information hiding, logistics privacy, and personal affairs.

Observations of three types of pulses in an erbium-doped fiber laser by incorporating a graphene saturable absorber.

We experimentally observed three types of pulses generated in an erbium-doped fiber laser by incorporating a homemade graphene saturable absorber (GSA). The generated pulses from the laser oscillator include dual-wavelength dark pulses, fundamentally step-like pulses, and non-soliton second-harmonic pulses. These operation regimes are first reported by using graphene as the saturable absorber. Our results will further indicate that the GSA can function well for obtaining various ultrafast pulse phenomena, highlighting the practical potential of graphene in ultrafast photonics technologies.