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Synthesis and reactivity of a bis(dimesitylboryl)azaborine and its fluoride sensing ability.
Agou, Tomohiro; Sekine, Masaki; Kobayashi, Junji; Kawashima, Takayuki.
Afiliação
  • Agou T; Department of Chemistry, Graduate School of Science, The University of Tokyo, Bunkyo-ku, Tokyo, Japan.
Chem Commun (Camb) ; (14): 1894-6, 2009 Apr 14.
Article em En | MEDLINE | ID: mdl-19319437
ABSTRACT
An azaborine bearing two dimesitylboryl groups on its periphery showed very strong light absorption and moderate photo-luminescence emission; the reaction of the title compound with fluoride ion resulted in multi-step fluoride ion complexation on the boron atoms of the dimesitylboryl groups, producing mono- and bisfluoroborates.

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2009 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2009 Tipo de documento: Article