N-Nosyl Oxaziridines as Terminal Oxidants in Copper(II)-Catalyzed Olefin Oxyaminations.
Tetrahedron Lett
; 51(40): 5223-5225, 2010 Oct 06.
Article
em En
| MEDLINE
| ID: mdl-21076655
ABSTRACT
We report that N-4-nosyl-3-phenyloxaziridine is an effective terminal oxidant for copper(II)-catalyzed oxyamination recently developed in our labs. This oxaziridine can be prepared on multi-gram scale and is easily purified by recrystallization. The products of oxyamination using this oxaziridine bear protecting groups that can be readily removed in high yields under mild conditions.
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MEDLINE
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En
Ano de publicação:
2010
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Article