3,3'-Bis(3,4,5-trimethoxy-benzo-yl)-1,1'-(o-phenyl-ene)dithio-urea ethanol solvate.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 8): o1632-3, 2008 Jul 31.
Article
em En
| MEDLINE
| ID: mdl-21203322
In the mol-ecule of the title compound, C(28)H(30)N(4)O(8)S(2)·C(2)H(6)O, the benzene ring is oriented at dihedral angles of 38.50â
(6) and 5.68â
(5)° with respect to the trimethoxy-phenyl rings, while the two trimethoxy-phenyl rings are oriented at a dihedral angle of 44.18â
(5)°. Intra-molecular N-Hâ¯O and N-Hâ¯S hydrogen bonds result in the formation of non-planar six-, seven- and eight-membered rings. The twisting modes of the two side arms are different [C-N-C-O and C-N-C-N torsion angles = 0.1â
(3) and 11.8â
(3)°, respectively, in one arm, and 4.6â
(3) and -11.5â
(3)° in the other]. In the crystal structure, inter-molecular N-Hâ¯O and O-Hâ¯O hydrogen bonds link the mol-ecules.
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MEDLINE
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Ano de publicação:
2008
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Article