Elusive Double-Eight-Ring Zeolitic Secondary Building Unit.
J Am Chem Soc
; 139(1): 59-62, 2017 01 11.
Article
em En
| MEDLINE
| ID: mdl-27989116
ABSTRACT
The double-eight-ring (D8R), an elusive secondary building unit of zeolites, has been stabilized for the first time, both in solution and solid-state. The present study further establishes that any of the three double-ring building blocks of zeolites, viz. D4R, D6R and D8R ([ArPO3Zn(L)]n (n = 4, 6 or 8)), can be preferentially isolated (over the other two) through a careful choice of metal source, aryl phosphate and ancillary ligand, apart from maintaining a meticulous control on the reaction conditions.
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MEDLINE
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En
Ano de publicação:
2017
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Article