Ruthenium(II)-Catalyzed meta C-H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation.
Angew Chem Int Ed Engl
; 56(8): 2045-2049, 2017 02 13.
Article
em En
| MEDLINE
| ID: mdl-28106316
ABSTRACT
Ruthenium(II)-catalyzed meta-selective C-H (di)fluoromethylation was accomplished by phosphine and carboxylate cooperation. The remote C-H functionalization was characterized by ample substrate scope, thereby setting the stage for meta-(di)fluoromethylation through facile C-H cleavage.
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MEDLINE
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En
Ano de publicação:
2017
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Article