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Ruthenium(II)-Catalyzed meta C-H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation.
Ruan, Zhixiong; Zhang, Shou-Kun; Zhu, Cuiju; Ruth, Paul Niklas; Stalke, Dietmar; Ackermann, Lutz.
Afiliação
  • Ruan Z; Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
  • Zhang SK; Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
  • Zhu C; Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
  • Ruth PN; Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstrasse 4, 37077, Göttingen, Germany.
  • Stalke D; Institut für Anorganische Chemie, Georg-August-Universität Göttingen, Tammannstrasse 4, 37077, Göttingen, Germany.
  • Ackermann L; Institut für Organische und Biomolekulare Chemie, Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
Angew Chem Int Ed Engl ; 56(8): 2045-2049, 2017 02 13.
Article em En | MEDLINE | ID: mdl-28106316
ABSTRACT
Ruthenium(II)-catalyzed meta-selective C-H (di)fluoromethylation was accomplished by phosphine and carboxylate cooperation. The remote C-H functionalization was characterized by ample substrate scope, thereby setting the stage for meta-(di)fluoromethylation through facile C-H cleavage.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2017 Tipo de documento: Article