Unravelling the Structure and Electrochemical Performance of Li-Cr-Mn-O Cathodes: From Spinel to Layered.
ACS Appl Mater Interfaces
; 10(10): 8827-8835, 2018 Mar 14.
Article
em En
| MEDLINE
| ID: mdl-29470046
ABSTRACT
To explore a new series of cathode materials with high electrochemical performance, the spinel-layered (1 - x)[LiCrMnO4]· x[Li2MnO3·LiCrO2] ( x = 0, 0.25, 0.5, 0.75, and 1) composites are synthesized with the sol-gel method. X-ray diffraction, high-resolution transmission electron microscopy, selected area electron diffraction, and Raman spectra reveal that the structure of the (1 - x)[LiCrMnO4]· x[Li2MnO3·LiCrO2] cathode materials evolves from spinel to hybrid spinel-layered and layered structures with the increase of the Li concentration. Test results reveal that the structure and electrochemical performance of (1 - x)[LiCrMnO4]· x[Li2MnO3·LiCrO2] ( x = 0.25, 0.5 and 0.75) composites have the characteristics of both spinel ( x = 0) and Li-rich layered phases ( x = 1). In particular, x = 0.5 and 0.75 electrodes exhibit relatively high capacity retention and rate capability, which is mainly ascribed to the synergistic effect of the spinel and Li-rich layered phases, the 3D Li-ion diffusion channels of the spinel phase, and the low charge-transfer resistance ( Rct) and Warburg diffusion impedance ( Wo).
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MEDLINE
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En
Ano de publicação:
2018
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Article