Cobalt(II) Coordination Polymer as a Precatalyst for Selective Hydroboration of Aldehydes, Ketones, and Imines.
J Org Chem
; 83(16): 9442-9448, 2018 08 17.
Article
em En
| MEDLINE
| ID: mdl-29932672
ABSTRACT
Highly effective hydroboration precatalyst is developed based on a cobalt(II)-terpyridine coordination polymer (CP). The hydroboration of ketones, aldehydes, and imines with pinacolborane (HBpin) has been achieved using the recyclable CP catalyst in the presence of an air-stable activator. A wide range of substrates containing polar CâO or CâN bonds have been hydroborated selectively in excellent yields under ambient conditions.
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Base de dados:
MEDLINE
Idioma:
En
Ano de publicação:
2018
Tipo de documento:
Article