Approaching the Lithiation Limit of MoS2 While Maintaining Its Layered Crystalline Structure to Improve Lithium Storage.
Angew Chem Int Ed Engl
; 58(11): 3521-3526, 2019 Mar 11.
Article
em En
| MEDLINE
| ID: mdl-30624844
ABSTRACT
MoS2 holds great promise as high-rate electrode for lithium-ion batteries since its large interlayer can allow fast lithium diffusion in 3.0-1.0â
V. However, the low theoretical capacity (167â
mAh g-1 ) limits its wide application. Here, by fine tuning the lithiation depth of MoS2 , we demonstrate that its parent layered structure can be preserved with expanded interlayers while cycling in 3.0-0.6â
V. The deeper lithiation and maintained crystalline structure endows commercially micrometer-sized MoS2 with a capacity of 232â
mAh g-1 at 0.05â
A g-1 and circa 92 % capacity retention after 1000 cycles at 1.0â
A g-1 . Moreover, the enlarged interlayers enable MoS2 to release a capacity of 165â
mAh g-1 at 5.0â
A g-1 , which is double the capacity obtained under 3.0-1.0â
V at the same rate. Our strategy of controlling the lithiation depth of MoS2 to avoid fracture ushers in new possibilities to enhance the lithium storage of layered transition-metal dichalcogenides.
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MEDLINE
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En
Ano de publicação:
2019
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Article