Ni-Co Selenide Nanosheet/3D Graphene/Nickel Foam Binder-Free Electrode for High-Performance Supercapacitor.
ACS Appl Mater Interfaces
; 11(8): 7946-7953, 2019 Feb 27.
Article
em En
| MEDLINE
| ID: mdl-30721020
ABSTRACT
Transition-metal selenide electrodes have recently attracted increasing interest in supercapacitors resulting from their superior electrochemical performance, lower-cost, and environmental friendliness. Herein, we report a novel bimetallic Ni-Co selenide nanosheet/three-dimensional (3D) graphene/nickel foam binder-free electrode (NiCo2.1Se3.3 NSs/3D G/NF) prepared via chemical vapor deposition followed by a simple two-step hydrothermal process in this paper. The NiCo2.1Se3.3 NSs array vertically on 3D G/NF with a uniform and stable structure without using any chemical binders. This novel electrode is flexible, highly conductive, and exhibits an excellent specific capacitance of â¼742.4 F g-1 at 1 mA cm-2. Furthermore, with a 10-fold increase to 10 mA cm-2, it still retains 471.78 F g-1 and a high cycling stability of â¼83.8% of the initial retention after 1000 cycles at 10 mA cm-2, demonstrating that NiCo2.1Se3.3 NSs/3D G/NF binder-free electrode has potential for energy storage application in high-performance supercapacitor fields.
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2019
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Article