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Precise regulation of the selectivity of supported nano-Pd catalysts using polysiloxane coatings with tunable surface wettability.
Wang, Hongli; Gao, Ziqian; Wang, Xinzhi; Wei, Ruiping; Zhang, Junping; Shi, Feng.
Afiliação
  • Wang H; State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. China. jpzhang@licp.cas.cn fshi@licp.cas.cn.
  • Gao Z; State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. China. jpzhang@licp.cas.cn fshi@licp.cas.cn.
  • Wang X; State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. China. jpzhang@licp.cas.cn fshi@licp.cas.cn and University of Chinese Academy of Sciences, No. 19A, Yuquanlu, Beijing 100049, P. R. China.
  • Wei R; State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. China. jpzhang@licp.cas.cn fshi@licp.cas.cn and University of Chinese Academy of Sciences, No. 19A, Yuquanlu, Beijing 100049, P. R. China.
  • Zhang J; State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. China. jpzhang@licp.cas.cn fshi@licp.cas.cn and Research & Development Center for Eco-materials and Eco-chemistry, Lanzhou Institute of
  • Shi F; State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics (LICP), Chinese Academy of Sciences, Lanzhou 730000, P. R. China. jpzhang@licp.cas.cn fshi@licp.cas.cn.
Chem Commun (Camb) ; 55(57): 8305-8308, 2019 Jul 11.
Article em En | MEDLINE | ID: mdl-31250846
ABSTRACT
A facile method was developed for surface modification of supported nano-Pd catalysts with tailorable wettability. The obtained Pd/TiO2@POS catalytic materials could be used in the controllable synthesis of styrene and ethylbenzene obtained from hydrogenation of phenylacetylene and the selective synthesis of imine and N-methylanilines via a reductive amination reaction. The precise modification of the hydrophilicity/hydrophobicity of the catalyst surface is crucial to realize this targeted transformation.
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2019 Tipo de documento: Article