Ambiphilicity of a mononuclear cobalt(III) superoxo complex.
Chem Commun (Camb)
; 56(94): 14821-14824, 2020 Nov 26.
Article
em En
| MEDLINE
| ID: mdl-33151205
ABSTRACT
Addition of HOTf to a mixture of CoIII(BDPP)(O2Ë) (1, H2BDPP = 2,6-bis((2-(S)-diphenylhydroxylmethyl-1-pyrrolidinyl)methyl)pyridine) and Cp*2Fe produced H2O2 in high yield implying formation of CoIII(BDPP)(OOH) (3), and reaction of Sc(OTf)3 with the same mixture gave a peroxo-bridged CoIII/ScIII5. These findings demonstrate the ambiphilic property of CoIII-superoxo 1.
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MEDLINE
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Ano de publicação:
2020
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Article